Production of H2 at fast rates using a nickel electrocatalyst in water-acetonitrile solutions

被引：79
作者：
Hoffert, Wesley A. [1 ]
Roberts, John A. S. [1 ]
Bullock, R. Morris [1 ]
Helm, Monte L. [1 ]
机构：
[1] Pacific NW Natl Lab, Div Phys Sci, Ctr Mol Electrocatalysis, Richland, WA 99352 USA
来源：
CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 71期
关键词：
HYDROGEN-PRODUCTION; CATALYTIC RATES; PENDANT AMINES; ACTIVE-SITE; COMPLEXES; COBALT; OXIDATION; GENERATION; REDUCTION;
D O I：
10.1039/c3cc43203c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We report a synthetic nickel complex containing proton relays, [Ni((P2N2C6H4OH)-N-Ph)(2)](BF4)(2) ((P2N2C6H4OH)-N-Ph = 1,5-bis(p-hydroxyphenyl)-3,7- diphenyl-1,5-diaza-3,7-diphosphacyclo-octane), that catalyzes the production of H-2 in aqueous acetonitrile with turnover frequencies of 750-170 000 s(-1) at experimentally determined overpotentials of 310-470 mV.
引用
收藏
页码：7767 / 7769
页数：3
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