Preparation of Pd nanoparticle-decorated hollow SnO2 nanofibers and their enhanced formaldehyde sensing properties

被引:101
作者
Lin, Ying [1 ]
Wei, Wei [1 ]
Li, Yujia [1 ]
Li, Feng [2 ]
Zhou, Jingran [1 ]
Sun, Dongming [1 ]
Chen, Yu [3 ]
Ruan, Shengping [2 ]
机构
[1] Jilin Univ, State Key Lab Integrated Optoelect, Changchun 130012, Peoples R China
[2] Jilin Univ, Coll Elect Sci & Engn, Changchun 130012, Peoples R China
[3] Chinese Acad Sci, Inst Semicond, Beijing 100083, Peoples R China
基金
中国国家自然科学基金;
关键词
Pd-decorated; SnO2; Hollow nanofiber; Formaldehyde sensor; GAS SENSOR; SHELL NANOREACTORS; ZNO; CO; PERFORMANCE; NANOSTRUCTURES; NANOBELTS; NANOWIRES; NANORODS; MICROSTRUCTURE;
D O I
10.1016/j.jallcom.2015.08.174
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The Pd nanoparticles decorated hollow SnO2 nanofibers (NFs) were synthesized by the electrospinning technique and the wet decorating process. The properties of the sensing material were characterized by X-Ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), transmission electron microscopy (TEM) and high-resolution transmission electron microscopy (HRTEM). Compared with the pure SnO2 NFs gas sensor, the optimum operating temperature of Pd decorated hollow SnO2 NFs gas sensor dropped to 160 degrees C from 180 degrees C. The response to 100 ppm formaldehyde (HCHO) was raised to 18.8 from 5.4. Furthermore, the response-recovery characteristics were enhanced a lot. It is believed that its high gas sensing performance is derived from the hollow structure and the catalysis of Pd nanoparticles. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:690 / 698
页数:9
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