Synthesis, physical properties and X-ray crystal structure of [(DMNP)(2)(MNP)(2)SiMo12O40 center dot 2DMF] a charge-transfer salt between organic donor and polyoxometalate acceptor

被引：39
作者：
Zhang, XM
Shan, BZ
You, XZ
Fun, HK
机构：
[1] NANJING UNIV,STATE KEY LAB COORDINAT CHEM,INST COORDINAT CHEM,NANJING 210093,PEOPLES R CHINA
[2] UNIV SAINS MALAYSIA,SCH PHYS,XRAY CRYSTALLOG UNIT,GEORGE TOWN 11800,PENANG,MALAYSIA
来源：
POLYHEDRON | 1997年 / 16卷 / 01期
关键词：
crystal structure; charge-transfer; donor; acceptor; polyoxometalate; Keggin structure;
D O I：
10.1016/0277-5387(96)00236-7
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The title complex [(DMNP)(2)(MNP)(2)SiMo12O40. 2DMF] (where DMNP is MeNC(5)H(4)NMe(2), MNP is MeNC(5)H(4)NHMe and DMF is N,N-dimethyl formamide) has been synthesized and characterized by elemental analysis, XPS, ESR and IR spectra studies. The X-ray crystal structure revealed that the title complex possesses a noncentrosymmetrical arrangement in the unit cell.
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页码：95 / 102
页数：8
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