A Two-Step Valence Tautomeric Transition in a Dinuclear Cobalt Complex

被引：58

作者：

Alley, Kerwyn G. ^{[1
]}

Poneti, Giordano ^{[2
,3
,4
]}

Aitken, Jade B. ^{[5
,6
,7
]}

Hocking, Rosalie K. ^{[8
]}

Moubaraki, Boujemaa ^{[8
]}

Murray, Keith S. ^{[8
]}

Abrahams, Brendan F. ^{[1
]}

Harris, Hugh H. ^{[9
]}

Sorace, Lorenzo ^{[2
,3
]}

Boskovic, Colette ^{[1
]}

机构：

[1] Univ Melbourne, Sch Chem, Melbourne, Vic 3010, Australia

[2] Univ Florence, UdR INSTM, I-50019 Sesto Fiorentino, FL, Italy

[3] Univ Florence, Dept Chem, I-50019 Sesto Fiorentino, FL, Italy

[4] Guglielmo Marconi Univ, Dept Appl Sci & Technol, I-00193 Rome, Italy

[5] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia

[6] Australian Synchrotron, Clayton, Vic 3168, Australia

[7] KEK, Inst Mat Struct Sci, Tsukuba, Ibaraki 3050801, Japan

[8] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia

[9] Univ Adelaide, Sch Chem & Phys, Adelaide, SA 5005, Australia

来源：

INORGANIC CHEMISTRY | 2012年 / 51卷 / 07期

基金：

澳大利亚研究理事会;

关键词：

DIOXOLENE COMPLEX; TETRAOXOLENE COMPLEX; CHARGE-DISTRIBUTION; INTERCONVERSION;

D O I：

10.1021/ic3002527

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A dinuclear cobalt complex with cobalt centers bridged by a bis(dioxolene) ligand exhibits a rare two-step valence tautomeric transition.

引用

页码：3944 / 3946

页数：3

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