Model Based and Model Free Methods for Kinetic Study of Thermal Degradation of Cellulose Thiophosphinite Derivative

被引：0

作者：

Malhotra, Deepa ^{[1
]}

Kumar, Krishan ^{[1
]}

Dahiya, J. B. ^{[1
]}

机构：

[1] Guru Jambheshwar Univ Sci & Technol, Dept Chem, Hisar 125001, Haryana, India

来源：

ASIAN JOURNAL OF CHEMISTRY | 2009年 / 21卷 / 05期

关键词：

Cellulose diethylamino ammoniumthiophosphinite; Thermal degradation; Kinetics; Char; Coats-Redfern method; THERMOGRAVIMETRIC DATA; COTTON;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cellulose diethylamino ammoniumthiophosphinite (CEAAT) has been chosen for a study of its degradation behaviour from ambient temperature to 700 degrees C using thermogravimetry. Cellulose diethylamino ammoniumthiophosphinite when heated in helium atmosphere, gives rise to higher char yield (45 %) as compared to cellulose (9.1 %) at 700 degrees C. Kinetics was studied using model based and model free methods for degradation of CEAAT up to 700 degrees C. After taking into account the values of activation energy and pre-exponential factor both obtained by model free methods and comparing these values with the values obtained by model based method. The diffusion controlled and random nucleation type mechanisms are found the most probable during thermal degradation of CEAAT.

引用

页码：4104 / 4112

页数：9

共 50 条

[21] A Kinetic Model for Non-Oxidative Thermal Degradation of Nylon 66 [J].

Karimi, Hadiseh ;

Schaffer, Mark A. ;

McAuley, Kim B. .

MACROMOLECULAR REACTION ENGINEERING, 2012, 6 (2-3) :93-109

[22] Correlation between the cross-linking and degradation activation energy of cotton fabric treated with chitosan kinetic study by 'model-free' multiple heating rate methods [J].

Lal, Sohan ;

Arora, Sanjiv ;

Kumar, Vinod ;

Rani, Shikha ;

Jagdeva, Geetanjali .

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2021, 143 (04) :3267-3274

[23] Comprehensive kinetic study of thermal degradation of polyvinylchloride (PVC) [J].

Xu, Zhuo ;

Kolapkar, Shreyas S. ;

Zinchik, Stas ;

Bar-Ziv, Ezra ;

McDonald, Armando G. .

POLYMER DEGRADATION AND STABILITY, 2020, 176

[24] Application of Model-Free and Model-Based Kinetic Methods in Evaluation of Reactions Complexity during Thermo-Oxidative Degradation Process: Case Study of [4-(Hydroxymethyl)phenoxymethyl] Polystyrene Resin [J].

Jankovic, Bojan ;

Dodevski, Vladimir ;

Veljkovic, Filip ;

Jankovic, Marija ;

Manic, Nebojsa .

FIRE-SWITZERLAND, 2024, 7 (05)

[25] A new model for the kinetic analysis of thermal degradation of polymers driven by random scission [J].

Sanchez-Jimenez, Pedro E. ;

Perez-Maqueda, Luis A. ;

Perejon, Antonio ;

Criado, Jose M. .

POLYMER DEGRADATION AND STABILITY, 2010, 95 (05) :733-739

[26] Thermal degradation model of used surgical masks based on machine learning methodology [J].

Chaudhary, Abhishek S. ;

Kiran, Bandaru ;

Sivagami, K. ;

Govindarajan, Dhivakar ;

Chakraborty, Samarshi .

JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS, 2023, 144

[27] Kinetic study on the thermal degradation of polypropylene and polyethylene [J].

Bockhorn, H ;

Hornung, A ;

Hornung, U ;

Schwaller, D .

JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 1999, 48 (02) :93-109

[28] Thermal decomposition kinetics of sodium perborate tetrahydrate to sodium metaborate by using model-fitting and model-free methods [J].

Demir, Halil .

KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2011, 28 (10) :2002-2008

[29] Kinetic studies on the pyrolysis of plastic waste using a combination of model-fitting and model-free methods [J].

Yao, Zhitong ;

Yu, Shaoqi ;

Su, Weiping ;

Wu, Weihong ;

Tang, Junhong ;

Qi, Wei .

WASTE MANAGEMENT & RESEARCH, 2020, 38 (38) :77-85

[30] Kinetic Study of Thermal Degradation of Hazardous Organic Compounds in Different Atmospheres [J].

Xiao, Haiping ;

Ru, Yu ;

Yan, Dahai ;

Li, Li ;

Sun, Xiaowan ;

Wang, Ning ;

He, Jie ;

Huang, Qifei .

ENVIRONMENTAL ENGINEERING SCIENCE, 2018, 35 (03) :159-168

← 1 2 3 4 5 →