Preparation of esters and amides from carboxylic acids and N-formylation of amines promoted by 1,3,5-triazo-2,4,6-triphosphorine-2,2,4,4,6,6-hexachloride (TAPC)

被引：27
作者：
Bahrami, Kiumars [1 ,2 ]
Khodaei, Mohammad M. [1 ]
Targhan, Homa [1 ]
Arabi, Mehdi Sheikh [1 ]
机构：
[1] Razi Univ, Dept Organ Chem, Fac Chem, Kermanshah 6714967346, Iran
[2] Razi Univ, NNRC, Kermanshah 6714967346, Iran
来源：
TETRAHEDRON LETTERS | 2013年 / 54卷 / 37期
关键词：
Organic esters; Carboxamides; N-formylation; Grinding technique; Carboxylic acids; Protection of functional groups; ROOM-TEMPERATURE; EFFICIENT PROCEDURE; SECONDARY-AMINES; USEFUL REAGENT; FACILE METHOD; FORMIC-ACID; CATALYST; MILD; DERIVATIVES; AMIDATION;
D O I：
10.1016/j.tetlet.2013.07.033
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new method is described for the preparation of esters and amides promoted by TAPC from carboxylic acids using a solvent-free grinding technique. The solvent-free N-formylation of amines is also reported. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码：5064 / 5068
页数：5
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