Syntheses and structural characterizations of cis-[M(NO)2(CNXyl)4]+ (M = Nb, Ta; Xyl=2,6-Me2C6H3).: The first dinitrosyls of niobium and tantalum

被引：10

作者：

Barybin, MV ^{[1
]}

Young, VG ^{[1
]}

Ellis, JE ^{[1
]}

机构：

[1] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA

来源：

ORGANOMETALLICS | 1999年 / 18卷 / 15期

关键词：

D O I：

10.1021/om990330w

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first dinitrosyls of niobium and tantalum, cis-[M(NO)(2)(CNXyl)(4)](+), have been prepared by direct nitrosylation of [M(CO)(6)](-) (M = Nb, Ta) with 2 equiv of [NO](+) in, the presence of 2,6-dimethylphenyl isocyanide, CNXyl. These new complexes have been fully characterized by IR, H-1, and C-13 NMR spectra as well as X-ray crystallography.

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页码：2744 / 2746

页数：3

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