Copper-catalyzed direct and odorless selenylation with a sodium selenite-based reagent

被引：28
作者：
Cao, Yuan [1 ]
Liu, Jie [1 ]
Liu, Fanmin [1 ]
Jiang, Lvqi [1 ]
Yi, Wenbin [1 ]
机构：
[1] Nanjing Univ Sci & Technol, Sch Chem Engn, Nanjing 210094, Jiangsu, Peoples R China
来源：
ORGANIC CHEMISTRY FRONTIERS | 2019年 / 6卷 / 06期
基金：
中国国家自然科学基金;
关键词：
SELENOORGANIC COMPOUND EBSELEN; ANTIOXIDANT PROPERTIES; DIRECT SELENATION; C(SP(2))-H BONDS; ORGANOSELENIUM; THIOREDOXIN; INHIBITION; INDOLES; ACID; ARYL;
D O I：
10.1039/c8qo01355a
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new method using a sodium selenite-based (NaO2SeR) direct selenylation reagent has been developed. NaO2SeR is odorless, shelf-stable, easy to handle, practical and scalable. Good yields and a broad functional group compatibility were observed when it was reacted with indoles, a furan, pyrrole and ketones under reductive conditions to afford the corresponding organoselenium products.
引用
收藏
页码：825 / 829
页数：5
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