Uranium-mediated ring opening of tetrahydrofuran. Crystal structure of UI2(OCH2CH2CH2CH2I)(2)(Ph(3)P=O)(2)

被引：69
作者：
Avens, LR [1 ]
Barnhart, DM [1 ]
Burns, CJ [1 ]
McKee, SD [1 ]
机构：
[1] LOS ALAMOS NATL LAB,LOS ALAMOS,NM 87545
来源：
INORGANIC CHEMISTRY | 1996年 / 35卷 / 02期
关键词：
D O I：
10.1021/ic9505211
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis and structure of the uranium(IV) compound UI2(OCH2CH2CH2CH2I)(2)(Ph(3)P=O)(2) (1) is described. Compound 1 is formed from the ring opening of THF from UI4(CH3CN)(4).
引用
收藏
页码：537 / &
页数：4
相关论文
共 48 条
  • [1] ACTINIDE STRUCTURAL STUDIES .1. CRYSTAL AND MOLECULAR-STRUCTURES OF DINITRATODIOXOBIS(TRIPHENYLPHOSPHINE OXIDE )NEPTUNIUM(VI), DINITRATODIOXOBIS(TRIPHENYLPHOSPHINE OXIDE )URANIUM(VI), AND DICHLORODIOXO(TRIPHENYLPHOSPHINE OXIDE )NEPTUNIUM(VI)
    ALCOCK, NW
    ROBERTS, MM
    BROWN, D
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1982, (01): : 25 - 31
  • [2] NMR STUDY OF MOLECULAR STRUCTURE AND CONFORMATIONAL MOBILITY OF PARAMAGNETIC ORGANOMETALLIC ALKOXY-URANIUM-(IV) COMPLEXES - TRIS(CYCLOPENTADIENYL)-HEXYLOXY-,-CYCLOHEXYLOXY-, AND CHOLESTERYLOXY-URANIUM-(IV)
    AMMON, RV
    FISCHER, RD
    KANELLAK.B
    [J]. CHEMISCHE BERICHTE-RECUEIL, 1972, 105 (01): : 45 - +
  • [3] AMMON RV, 1969, RADIOCHIM ACTA, V11, P162
  • [4] A CONVENIENT ENTRY INTO TRIVALENT ACTINIDE CHEMISTRY - SYNTHESIS AND CHARACTERIZATION OF ANI3(THF)4 AND AN[N(SIME3)2]3 (AN=U, NP, PU)
    AVENS, LR
    BOTT, SG
    CLARK, DL
    SATTELBERGER, AP
    WATKIN, JG
    ZWICK, BD
    [J]. INORGANIC CHEMISTRY, 1994, 33 (10) : 2248 - 2256
  • [5] AVENS LR, UNPUB
  • [6] CRYSTAL-STRUCTURE OF PENTACHLORO(TRIPHENYLPHOSPHINE OXIDE) URANIUM(V)
    BOMBIERI, G
    BROWN, D
    MEALLI, C
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1976, (20): : 2025 - 2029
  • [7] TRIPHENYLPHOSPHINE OXIDE COMPLEXES OF ACTINIDE TETRAHALIDES - CRYSTAL AND MOLECULAR-STRUCTURE OF TRANS-TETRABROMOBIS(TRIPHENYLPHOSPHINE OXIDE)URANIUM(IV)
    BOMBIERI, G
    BENETOLLO, F
    BAGNALL, KW
    PLEWS, MJ
    BROWN, D
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1983, (02): : 343 - 348
  • [8] CRYSTAL AND MOLECULAR-STRUCTURE OF TETRACHLOROBIS(TRIPHENYLPHOSPHINE OXIDE)URANIUM(IV)
    BOMBIERI, G
    BROWN, D
    GRAZIANI, R
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1975, (18): : 1873 - 1876
  • [9] CRYSTAL AND MOLECULAR-STRUCTURE OF "DICHLORODIOXOBIS(TRIPHENYLPHOSPHINE OXIDE)URANIUM(VI)
    BOMBIERI, G
    FORSELLINI, E
    DAY, JP
    AZEEZ, WI
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1978, (06): : 677 - 680
  • [10] SUBSTITUTION OR NUCLEOPHILIC-ATTACK BY PHOSPHINES ON ZRCL4(THF)2
    BREEN, TL
    STEPHAN, DW
    [J]. INORGANIC CHEMISTRY, 1992, 31 (19) : 4019 - 4022
12345