Uranium-mediated ring opening of tetrahydrofuran. Crystal structure of UI2(OCH2CH2CH2CH2I)(2)(Ph(3)P=O)(2)

被引:69
作者
Avens, LR [1 ]
Barnhart, DM [1 ]
Burns, CJ [1 ]
McKee, SD [1 ]
机构
[1] LOS ALAMOS NATL LAB,LOS ALAMOS,NM 87545
关键词
D O I
10.1021/ic9505211
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The synthesis and structure of the uranium(IV) compound UI2(OCH2CH2CH2CH2I)(2)(Ph(3)P=O)(2) (1) is described. Compound 1 is formed from the ring opening of THF from UI4(CH3CN)(4).
引用
收藏
页码:537 / &
页数:4
相关论文
共 48 条
[1]   ACTINIDE STRUCTURAL STUDIES .1. CRYSTAL AND MOLECULAR-STRUCTURES OF DINITRATODIOXOBIS(TRIPHENYLPHOSPHINE OXIDE )NEPTUNIUM(VI), DINITRATODIOXOBIS(TRIPHENYLPHOSPHINE OXIDE )URANIUM(VI), AND DICHLORODIOXO(TRIPHENYLPHOSPHINE OXIDE )NEPTUNIUM(VI) [J].
ALCOCK, NW ;
ROBERTS, MM ;
BROWN, D .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1982, (01) :25-31
[2]   NMR STUDY OF MOLECULAR STRUCTURE AND CONFORMATIONAL MOBILITY OF PARAMAGNETIC ORGANOMETALLIC ALKOXY-URANIUM-(IV) COMPLEXES - TRIS(CYCLOPENTADIENYL)-HEXYLOXY-,-CYCLOHEXYLOXY-, AND CHOLESTERYLOXY-URANIUM-(IV) [J].
AMMON, RV ;
FISCHER, RD ;
KANELLAK.B .
CHEMISCHE BERICHTE-RECUEIL, 1972, 105 (01) :45-+
[3]  
AMMON RV, 1969, RADIOCHIM ACTA, V11, P162
[4]   A CONVENIENT ENTRY INTO TRIVALENT ACTINIDE CHEMISTRY - SYNTHESIS AND CHARACTERIZATION OF ANI3(THF)4 AND AN[N(SIME3)2]3 (AN=U, NP, PU) [J].
AVENS, LR ;
BOTT, SG ;
CLARK, DL ;
SATTELBERGER, AP ;
WATKIN, JG ;
ZWICK, BD .
INORGANIC CHEMISTRY, 1994, 33 (10) :2248-2256
[5]  
AVENS LR, UNPUB
[6]   CRYSTAL-STRUCTURE OF PENTACHLORO(TRIPHENYLPHOSPHINE OXIDE) URANIUM(V) [J].
BOMBIERI, G ;
BROWN, D ;
MEALLI, C .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1976, (20) :2025-2029
[7]   TRIPHENYLPHOSPHINE OXIDE COMPLEXES OF ACTINIDE TETRAHALIDES - CRYSTAL AND MOLECULAR-STRUCTURE OF TRANS-TETRABROMOBIS(TRIPHENYLPHOSPHINE OXIDE)URANIUM(IV) [J].
BOMBIERI, G ;
BENETOLLO, F ;
BAGNALL, KW ;
PLEWS, MJ ;
BROWN, D .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1983, (02) :343-348
[8]   CRYSTAL AND MOLECULAR-STRUCTURE OF TETRACHLOROBIS(TRIPHENYLPHOSPHINE OXIDE)URANIUM(IV) [J].
BOMBIERI, G ;
BROWN, D ;
GRAZIANI, R .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1975, (18) :1873-1876
[9]   CRYSTAL AND MOLECULAR-STRUCTURE OF "DICHLORODIOXOBIS(TRIPHENYLPHOSPHINE OXIDE)URANIUM(VI) [J].
BOMBIERI, G ;
FORSELLINI, E ;
DAY, JP ;
AZEEZ, WI .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1978, (06) :677-680
[10]   SUBSTITUTION OR NUCLEOPHILIC-ATTACK BY PHOSPHINES ON ZRCL4(THF)2 [J].
BREEN, TL ;
STEPHAN, DW .
INORGANIC CHEMISTRY, 1992, 31 (19) :4019-4022