Polar and nonpolar phases of BiMO3: A review

被引：139

作者：

Belik, Alexei A. ^{[1
]}

机构：

[1] Natl Inst Mat Sci, Int Ctr Mat Nanoarchitecton WPI MANA, Tsukuba, Ibaraki 3050044, Japan

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2012年 / 195卷

基金：

日本学术振兴会;

关键词：

Ferroelectrics; Multiferroics; BiMnO3; BiCrO3; Polar crystal structure; High-pressure synthesis; NEUTRON POWDER DIFFRACTION; CENTROSYMMETRIC CRYSTAL-STRUCTURE; HIGH-PRESSURE SYNTHESIS; MAGNETIC GROUND-STATE; OPTICAL-PROPERTIES; TEMPERATURE POLYMORPHISM; MULTIFERROIC BIMNO3; AC MAGNETIZATION; PEROVSKITE; 1ST-PRINCIPLES;

D O I：

10.1016/j.jssc.2012.01.025

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Simple Bi-based compounds, BiMO3, are quite interesting materials. They offer large variations in crystal symmetries, polarity, and properties. Their chemical simplicity makes them ideal systems for materials fabrications, theoretical understanding, and thin-film growths. They can only be prepared at high-pressure high-temperature conditions (except for BiFeO3) in a bulk form. Some of them can be stabilized in thin films (M=Al, Sc, Cr, Mn, and Fe). In this review, we collect and analyze the recent experimental and theoretical results on BiMO3 with M=Al, Sc, Ti, V. Cr, Mn, Co, Ni, Cu, Ga, In, and Rh. In addition, unresolved problems and desirable future experiments are emphasized especially for the highly controversial compound BiMnO3. (C) 2012 Elsevier Inc. All rights reserved.

引用

页码：32 / 40

页数：9

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