A silicon-tethered allenic Pauson-Khand reaction

被引：38

作者：

Brummond, KM ^{[1
]}

Sill, PC

Rickards, B

Geib, SJ

机构：

[1] Univ Pittsburgh, Dept Chem, Pittsburgh, PA 15206 USA

[2] W Virginia Univ, Dept Chem, Morgantown, WV 26506 USA

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 20期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/S0040-4039(02)00633-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This manuscript describes a silicon-tethered Pauson-Khand reaction and subsequent cleavage of the resulting vinyl silane to afford functionalized alkylidene cyclopentenones. Altering the reaction conditions affords a selective reaction with either pi-bond of the allene. (C) 2002 Published by Elsevier Science Ltd.

引用

页码：3735 / 3738

页数：4

共 34 条

[1]

BOIS M, 1995, CHEM REV, V95, P1253

[2] Recent advances in the Pauson-Khand reaction and related [2+2+1] cycloadditions [J].