Synthesis of soluble main-chain poly(quinolines)

被引：3

作者：

Economopoulos, S. P.

Andreopoulou, A. K.

Gregoriou, V. G.

Kallitsis, J. K. ^{[1
]}

机构：

[1] Univ Patras, Dept Chem, Patras 26500, Greece

[2] Fdn Res & Technol Hellas, Inst Chem Engn & High Temp Proc, Patras, Greece

来源：

JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY | 2006年 / 43卷 / 07期

关键词：

quinolines; optical characterization; cyclic voltammetry; synthesis; electron transporters;

D O I：

10.1080/10601320600739662

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Polyquinoline polymers incorporating a bisquinoline moiety along their polymeric backbones have been synthesized and fully characterized. Two different macromolecular architectures were created; either fully conjugated or rigid-flexible main chains with both cases showing improved solubilities in common organic solvents. The monomers' and subsequent polymers' initial characterization was performed by NMR, as well as GPC and DSC techniques. Additionally, the polymers optical properties were evaluated using UV-Vis and PL spectroscopies. Cyclic voltammetry measurements provided information on the electrochemical properties and energy levels (HOMO-LUMO) of the final polyquinolines in order to determine possible applications in electronic devices.

引用

收藏

页码：977 / 988

页数：12

相关论文

共 41 条

[1] PHOTOCONDUCTIVITY IN CONJUGATED RIGID-ROD POLYQUINOLINES [J].

ABKOWITZ, MA ;

STOLKA, M ;

ANTONIADIS, H ;

AGRAWAL, AK ;

JENEKHE, SA .

SOLID STATE COMMUNICATIONS, 1992, 83 (11) :937-941

[2] 3RD-ORDER NONLINEAR OPTICAL-PROPERTIES OF CONJUGATED RIGID-ROD POLYQUINOLINES [J].

AGRAWAL, AK ;

JENEKHE, SA ;

VANHERZEELE, H ;

METH, JS .

JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (07) :2837-2843

[3] Nanolayered heterojunctions of donor and acceptor conjugated polymers of interest in light emitting and photovoltaic devices: Photoinduced electron transfer at polythiophene/polyquinoline interfaces [J].

Alam, MM ;

Jenekhe, SA .

JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (13) :2479-2482

[4] From terphenyl-dendronized macromonomers to aromatic-aliphatic polyethers bearing two pendant dendrons per repeating unit [J].

Andreopoulou, AK ;

Kallitsis, JK .

MACROMOLECULES, 2002, 35 (15) :5808-5815

[5]

[Anonymous], 1972, Inorg. Synth, DOI DOI 10.1002/9780470132449.CH23

[6] Quinoline-containing, conjugated poly(aryleneethynylene)s:: Novel metal and H+-responsive materials [J].

Bangcuyo, CG ;

Rampey-Vaughn, ME ;

Quan, LT ;

Angel, SM ;

Smith, MD ;

Bunz, UHF .

MACROMOLECULES, 2002, 35 (05) :1563-1568

[7] SYNTHESIS AND THERMAL-PROPERTIES OF AROMATIC POLYMERS CONTAINING 3,6-QUINOLINE UNITS IN THE MAIN CHAIN [J].

BEEVER, WH ;

STILLE, JK .

MACROMOLECULES, 1979, 12 (06) :1033-1038

[8] Photochromism and electrical transport characteristics of a dyad and a polymer with diarylethene and quinoline units [J].

Choi, H ;

Lee, H ;

Kang, YJ ;

Kim, E ;

Kang, SO ;

Ko, J .

JOURNAL OF ORGANIC CHEMISTRY, 2005, 70 (21) :8291-8297

[9] CONDENSATION OF AROMATIC NITRO COMPOUNDS WITH ACRYLACETONITRILES .2. SOME PARA-SUBSTITUTED NITROBENZENES [J].

DAVIS, RB ;

PIZZINI, LC .

JOURNAL OF ORGANIC CHEMISTRY, 1960, 25 (11) :1884-1888

[10] Synthesis and optical properties of new end-functionalized polyquinolines [J].

Economopoulos, SP ;

Andreopoulou, AK ;

Gregoriou, VG ;

Kallitsis, JK .

CHEMISTRY OF MATERIALS, 2005, 17 (05) :1063-1071

← 1 2 3 4 5 →