Thermal degradation characteristics of a novel flame retardant coating using TG-IR technique

被引：103

作者：

Chen, Xilei ^{[1
]}

Jiao, Chuanmei ^{[1
]}

机构：

[1] Qingdao Univ Sci & Technol, Coll Environm & Safety Engn, Qingdao 266042, Peoples R China

来源：

POLYMER DEGRADATION AND STABILITY | 2008年 / 93卷 / 12期

关键词：

UV curing; Phosphate; Flame retardant; Thermal degradation;

D O I：

10.1016/j.polymdegradstab.2008.09.005

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A novel phosphate acrylate monomer (TGMAP) has been synthesized by allowing phosphoric acid to react with glycidyl methacrylate. Its structure was characterized by Fourier transformed infrared spectroscopy (FTIR) and (1)H nuclear magnetic resonance spectroscopy ((1)H NMR). The thermal degradation mechanism was characterized using thermogravimetric analysis/infrared spectrometry (TG-IR). The char yield was 36.3% at 600 degrees C. TG data indicate that the material undergoes degradation in three characteristic temperature stages, which can be attributed to the decomposition of the phosphate, thermal pyrolysis of aliphatic chains, and degradation of an unstable structure in char, respectively. The volatilized products formed on thermal degradation of TGMAP indicated that the volatilized products are CO, CO(2), carboxylic acid, acid anhydride, water, alkane, and aromatic compounds according to the temperature of onset formation. Crown Copyright (C) 2008 Published by Elsevier Ltd. All rights reserved.

引用

页码：2222 / 2225

页数：4

共 13 条

[1] A novel phosphorus-containing polymer as a highly effective flame retardant [J].

Chang, YL ;

Wang, YZ ;

Ban, DM ;

Yang, B ;

Zhao, GM .

MACROMOLECULAR MATERIALS AND ENGINEERING, 2004, 289 (08) :703-707

[2] Cultivation-independent and -dependent characterization of Bacteria resident beneath John Evans Glacier [J].

Cheng, Stephanie M. ;

Foght, Julia M. .

FEMS MICROBIOLOGY ECOLOGY, 2007, 59 (02) :318-330

[3] Thermal behavior and degradation mechanism of poly(bisphenyl acryloxyethyl phosphate) as a UV curable flame-retardant oligomer [J].

Huang, Zhanguang ;

Shi, Wenfang .

POLYMER DEGRADATION AND STABILITY, 2006, 91 (08) :1674-1684

[4] Thermal behaviour and degradation mechanism of phosphate di/triacrylate used for UV curable flame-retardant coatings [J].

Liang, H ;

Shi, WF .

POLYMER DEGRADATION AND STABILITY, 2004, 84 (03) :525-532

[5] Photopolymerization and thermal behavior of phosphate diacrylate and triacrylate used as reactive-type flame-retardant monomers in ultraviolet-curable resins [J].

Liang, HB ;

Asif, A ;

Shi, WF .

JOURNAL OF APPLIED POLYMER SCIENCE, 2005, 97 (01) :185-194

[6] Phosphorus-containing epoxy for flame retardance .4. Kinetics and mechanism of thermal degradation [J].

Liu, YL ;

Hsiue, GH ;

Lan, CW ;

Chiu, YS .

POLYMER DEGRADATION AND STABILITY, 1997, 56 (03) :291-299

[7] Flammability and thermal degradation of flame retarded polypropylene composites containing melamine phosphate and pentaerythritol derivatives [J].

Lv, P ;

Wang, ZZ ;

Hu, KL ;

Fan, WC .

POLYMER DEGRADATION AND STABILITY, 2005, 90 (03) :523-534

[8] New UV curing systems for automotive applications [J].

Maag, K ;

Lenhard, W ;

Löffles, H .

PROGRESS IN ORGANIC COATINGS, 2000, 40 (1-4) :93-97

[9] Halogen-free flame retardant radiation curable coatings [J].

Randoux, T ;

Vanovervelt, JC ;

Van den Bergen, H ;

Camino, G .

PROGRESS IN ORGANIC COATINGS, 2002, 45 (2-3) :281-289

[10] Outdoor applications of UV curable clearcoats - a real alternative to thermally cured clearcoats [J].

Valet, A .

PROGRESS IN ORGANIC COATINGS, 1999, 35 (1-4) :223-233

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