A novel catalyst for alkene epoxidation:: a polymer-supported CoIILCl2 {L=2-(alkylthio)-3-phenyl-5-(pyridine-2-ylmethylene)-3,5-dihydro-4H-imidazole-4-one} complex

被引:31
作者
Beloglazkina, EK [1 ]
Majouga, AG [1 ]
Romashkina, RB [1 ]
Zyk, NV [1 ]
机构
[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119992, Russia
关键词
catalysis; epoxides; alkenes; cobalt(II); 2-(alkylthio)-3,5-dihydro-4H-imidazole-4-one complexes; polymer-supported complexes;
D O I
10.1016/j.tetlet.2006.02.098
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A polymer-supported complex based on 3-phenyl-5-(2-pyridylmethylidene)-2-thiohydantoin has been synthesized and employed as a catalyst for the epoxidation of alkenes using iodosylbenzene and hydrogen peroxide as oxidants. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2957 / 2959
页数:3
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