The interaction of N,N′-bis(2,6-dimethylphenyl)imidazol-2-ylidene with o-benzosemiquinonato zinc(II) and indium(III) complexes

被引：19
|
作者：
Ilyakina, Ekaterina V. [1 ]
Poddel'sky, Andrey I. [1 ]
Piskunov, Alexandr V. [1 ]
Fukin, Georgii K. [1 ]
Bogomyakov, Artem S. [2 ]
Cherkasov, Vladimir K. [1 ]
Abakumov, Gleb A. [1 ]
机构：
[1] Russian Acad Sci, GA Razuvaev Inst Organometall Chem, Nizhnii Novgorod 603950, Russia
[2] Russian Acad Sci, Int Tomog Ctr, Siberian Branch, Novosibirsk 630090, Russia
来源：
NEW JOURNAL OF CHEMISTRY | 2012年 / 36卷 / 10期
基金：
俄罗斯基础研究基金会;
关键词：
N-HETEROCYCLIC CARBENE; TRANSITION-METAL-COMPLEXES; MOLECULAR-STRUCTURE; LIGANDS; ALUMINUM; ADDUCTS; GALLIUM;
D O I：
10.1039/c2nj40490g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The N-heterocyclic carbene N,N'-bis(2,6-dimethylphenyl)imidazol-2-ylidene (NHC) interacts with non-transition metal complexes bearing redox-active o-benzosemiquinonato ligands in two ways: as a neutral donor or as a reducer. The reaction of NHC with (3,6-SQ)(2)Zn.Et2O gives the carbene adduct (3,6-SQ)(2)Zn.{CN(Me2Ph)(CH)(2)N(Me2Ph)} (1) while reaction with (3,6-SQ)(3)In forms the ionic complex [(3,6-SQ)(2)(3,6-Cat)In](-) {HCN(Me2Ph)(CH)(2)N(Me2Ph)}(+) (2) as the main product.
引用
收藏
页码：1944 / 1948
页数：5
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