Synthesis, crystal structure, and thermal properties of [Ir(NH3)5Cl][AuCl4]Cl

被引：0
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作者：
Plyusnin, PE [1 ]
Baidina, IA [1 ]
Shubin, YV [1 ]
Korenev, SV [1 ]
机构：
[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Div, Novosibirsk 630090, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2005年 / 50卷 / 12期
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D O I：
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中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A double complex salt [Ir(NH3)(5)Cl][AuCl4]Cl is synthesized and studied by X-ray diffraction. Its crystal data follows: a = 17.369(4) angstrom, b = 7.7990(16) angstrom, c = 11.218(2) angstrom, V = 1430.5(5) angstrom(3), space group C2/m, Z = 4, rho(calcd) = 3.19 g/cm(3), R = 0.0447. Thermolysis in air, hydrogen, and helium is studied.
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页码：1834 / 1840
页数：7
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