Silver(I) complexes of 2,2′;6′,4"-terpyridine:: The formation of discrete dimers versus helical polymers is anion dependent

被引：13

作者：

Beauchamp, DA ^{[1
]}

Loeb, SJ ^{[1
]}

机构：

[1] Univ Windsor, Dept Chem & Biochem, Windsor, ON N9B 3P4, Canada

来源：

SUPRAMOLECULAR CHEMISTRY | 2005年 / 17卷 / 08期

基金：

加拿大自然科学与工程研究理事会;

关键词：

nitrogen ligands; self-assembly; coordination polymer; helicate;

D O I：

10.1080/10610270500127162

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The ligand 2,2';6',4 double prime-terpyridine combines a chelating bipyridine group and terminal pyridine donor into a single molecule which is incapable of bonding all three donor N-atoms to a single metal center. Upon chelation to Ag(I), a pro-chiral, building block is produced which can subsequently aggregate by terminal coordination of the pyridine nitrogen. Two forms are possible; a discrete bimetallic complex with a center of symmetry and an infinite helical coordination polymer. Which of these structures occurs is dependent upon the counter anion.

引用

页码：617 / 622

页数：6

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