EPR and Mn-55 cw-ENDOR study of an antiferrogmagnetically coupled dinuclear manganese ((MnMnIV)-Mn-III) complex

被引：16
作者：
Zweygart, W
Bittl, R
Wieghardt, K
Lubitz, W
机构：
[1] TECH UNIV BERLIN,MAX VOLMER INST BIOPHYS CHEM & BIOCHEM,D-10623 BERLIN,GERMANY
[2] MAX PLANCK INST STRAHLENCHEM,D-45470 MULHEIM,GERMANY
来源：
CHEMICAL PHYSICS LETTERS | 1996年 / 261卷 / 03期
关键词：
D O I：
10.1016/0009-2614(96)00960-8
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
X- and Q-band EPR and Mn-55 cw-ENDOR experiments are reported on a binuclear ore-bridged dimanganese (MnMnIV)-Mn-III complex. Consistent simulations of spectra from both frequency bands using one parameter set for the orthorhombic g tensor and Mn-III and Mn-IV hyperfine tensors are achieved. Information on the manganese hyperfine couplings is independently obtained from Mn-55 cw-ENDOR spectroscopy performed on both ions.
引用
收藏
页码：272 / 276
页数：5
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