A Remarkably Simple Hybrid Surfactant-NHC Ligand, Its Gold-Complex, and Application in Micellar Catalysis

被引：46
作者：
Ruehling, Andreas [1 ]
Galla, Hans-Joachim [2 ]
Glorius, Frank [1 ]
机构：
[1] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany
[2] Univ Munster, Inst Biochem, D-48149 Munster, Germany
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2015年 / 21卷 / 35期
基金：
欧洲研究理事会;
关键词：
gold catalysis; green chemistry; micelles; N-heterocyclic carbenes; surfactant; CROSS-METATHESIS REACTIONS; HETEROCYCLIC CARBENES; OXIDATIVE ADDITION; ROOM-TEMPERATURE; WATER; HYDRATION; ALKYNES; KETONES; HYDROGENATION;
D O I：
10.1002/chem.201502542
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A combination of an N-heterocyclic carbene (NHC) ligand and a structurally simple surfactant has been realized, the hybrid surfactant-NHC. The related gold complex was synthesized, fully characterized, and applied in catalysis. This remarkably simple strategy allows, in combination with a co-surfactant, the application of gold catalysis in water.
引用
收藏
页码：12291 / 12294
页数：4
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