Conjugated microporous polymers consisting of tetrasubstituted [2.2]Paracyclophane junctions

被引：19

作者：

Morisaki, Yasuhiro ^{[1
]}

Gon, Masayuki ^{[1
]}

Chujo, Yoshiki ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Polymer Chem, Nishikyo Ku, Kyoto 6158510, Japan

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2013年 / 51卷 / 10期

关键词：

conjugated polymers; micropore; networks; 2.2]paracyclophane; polycondensation; ORDERED MESOPOROUS MATERIALS; INTRINSIC MICROPOROSITY; HYDROGEN STORAGE; ORGANIC POLYMERS; SURFACE-AREA; DESIGN; SPACE; METHANE; PIMS; CHEMISTRY;

D O I：

10.1002/pola.26600

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Conjugated microporous polymers (CMPs) were synthesized from the tetrasubstituted [2.2]paracyclophane skeleton as a tetra-functional building block using Hay coupling, Sonogashira-Hagihara cross-coupling, and Yamamoto coupling. The CMPs exhibited microporosity (less than 2 nm) and large surface areas (up to approximately 1000 m2 g-1). The CMPs consisted of relatively uniform particles and dispersed in organic solvents. Copyright © 2013 Wiley Periodicals, Inc.

引用

页码：2311 / 2316

页数：6

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