Conjugated microporous polymers consisting of tetrasubstituted [2.2]Paracyclophane junctions

被引：19
作者：
Morisaki, Yasuhiro [1 ]
Gon, Masayuki [1 ]
Chujo, Yoshiki [1 ]
机构：
[1] Kyoto Univ, Grad Sch Engn, Dept Polymer Chem, Nishikyo Ku, Kyoto 6158510, Japan
来源：
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2013年 / 51卷 / 10期
关键词：
conjugated polymers; micropore; networks; 2.2]paracyclophane; polycondensation; ORDERED MESOPOROUS MATERIALS; INTRINSIC MICROPOROSITY; HYDROGEN STORAGE; ORGANIC POLYMERS; SURFACE-AREA; DESIGN; SPACE; METHANE; PIMS; CHEMISTRY;
D O I：
10.1002/pola.26600
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Conjugated microporous polymers (CMPs) were synthesized from the tetrasubstituted [2.2]paracyclophane skeleton as a tetra-functional building block using Hay coupling, Sonogashira-Hagihara cross-coupling, and Yamamoto coupling. The CMPs exhibited microporosity (less than 2 nm) and large surface areas (up to approximately 1000 m2 g-1). The CMPs consisted of relatively uniform particles and dispersed in organic solvents. Copyright © 2013 Wiley Periodicals, Inc.
引用
收藏
页码：2311 / 2316
页数：6
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