A novel red-emitting nano-phosphor of Eu3+-doped LaBWO6

被引:47
作者
Huang, Yanlin [2 ]
Seo, Hyo Jin [1 ]
机构
[1] Pukyong Natl Univ, Dept Phys, Pusan 608737, South Korea
[2] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Peoples R China
关键词
Nanocrystalline materials; Luminescence; Phosphors; CRYSTAL-STRUCTURE; GROWTH;
D O I
10.1016/j.matlet.2012.06.051
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Eu3+-doped borotungstate La1-xEuxBWO6 (x=0.01-0.25) were synthesized by Pechini method. The red-emitting nano-phosphors were characterized by X-ray powder diffraction, scanning electron microscope and photoluminescence excitation and emission measurements. The optimal Eu3+ doping level of the phosphors was determined by the dependence of the red luminescence on the concentration. The abnormally high intensity of D-5(0)-> F-7(4) transition from Eu3+ ions was observed in La1-xEuxBWO6 (x=0.01-0.25). This nano-phosphor can be efficiently excited by near-ultraviolet and blue light to realize the far stronger red luminescence than the Y2O2S:Eu3+. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:107 / 109
页数:3
相关论文
共 17 条
[11]   Microwave-assisted synthesis of BaWO4 nanoparticles and its photoluminescence properties [J].
Shen, Yanhua ;
Li, Wen ;
Li, Taohai .
MATERIALS LETTERS, 2011, 65 (19-20) :2956-2958
[12]  
Stefanovich SY, 2001, RUSS J INORG CHEM+, V46, P1864
[13]   CRYSTAL STRUCTURE OF EUROPIUM TUNGSTATE [J].
TEMPLETON, DH ;
ZALKIN, A .
ACTA CRYSTALLOGRAPHICA, 1963, 16 (08) :762-&
[14]   Luminescence investigation of Eu3+ activated double molybdates red phosphors with scheelite structure [J].
Wang, Zhengliang ;
Liang, Hongbin ;
Gong, Menglian ;
Su, Qiang .
JOURNAL OF ALLOYS AND COMPOUNDS, 2007, 432 (1-2) :308-312
[15]   Structure determination and characterization of two rare-earth molybdenum borate compounds:: LnMoBO6 (Ln = La, Ce) [J].
Zhao, Dan ;
Cheng, Wen-Dan ;
Zhang, Hao ;
Hang, Shu-Ping ;
Fang, Ming .
DALTON TRANSACTIONS, 2008, (28) :3709-3714
[16]  
Zhu R, 2011, AM CERAM SOC BULL, V94, P3380
[17]   A Red-Emitting Phosphor of Eu-Based Borotungstate Eu3BWO9 for White Light-Emitting Diodes [J].
Zhu, Rui ;
Huang, Yanlin ;
Seo, Hyo Jin .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2010, 157 (12) :H1116-H1120