A novel red-emitting nano-phosphor of Eu3+-doped LaBWO6

被引:47
作者
Huang, Yanlin [2 ]
Seo, Hyo Jin [1 ]
机构
[1] Pukyong Natl Univ, Dept Phys, Pusan 608737, South Korea
[2] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Peoples R China
关键词
Nanocrystalline materials; Luminescence; Phosphors; CRYSTAL-STRUCTURE; GROWTH;
D O I
10.1016/j.matlet.2012.06.051
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Eu3+-doped borotungstate La1-xEuxBWO6 (x=0.01-0.25) were synthesized by Pechini method. The red-emitting nano-phosphors were characterized by X-ray powder diffraction, scanning electron microscope and photoluminescence excitation and emission measurements. The optimal Eu3+ doping level of the phosphors was determined by the dependence of the red luminescence on the concentration. The abnormally high intensity of D-5(0)-> F-7(4) transition from Eu3+ ions was observed in La1-xEuxBWO6 (x=0.01-0.25). This nano-phosphor can be efficiently excited by near-ultraviolet and blue light to realize the far stronger red luminescence than the Y2O2S:Eu3+. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:107 / 109
页数:3
相关论文
共 17 条
[1]   Raman spectroscopic study of structure of WO3-La2O3-B2O3 glasses with no color and crystallization of LaBWO6 [J].
Aleksandrov, L. ;
Komatsu, T. ;
Iordanova, R. ;
Dimitriev, Y. .
OPTICAL MATERIALS, 2011, 34 (01) :201-206
[2]   Nanostructuring in the process of the formation of mixed-anion compounds: Rare-earth borogermanates, germanophosphates, and borotungstates [J].
Bandurkin, G. A. ;
Chudinova, N. N. ;
Lysanova, G. V. ;
Palkina, K. K. ;
Murashova, E. V. ;
Krut'ko, V. A. ;
Balagina, G. M. .
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2006, 51 (02) :292-305
[3]   Eu substitution and particle size control Of Y2O2S for the excitation by UV light emitting diodes [J].
Chou, TW ;
Mylswamy, S ;
Liu, RS ;
Chuang, SZ .
SOLID STATE COMMUNICATIONS, 2005, 136 (04) :205-209
[4]   Top seeded solution growth and optical properties of a bromic borate crystal: K3B6O10Br [J].
Fan, Xiaoyun ;
Zhang, Min ;
Pan, Shilie ;
Yang, Yun ;
Zhao, Wenwu .
MATERIALS LETTERS, 2012, 68 :374-377
[5]   A theoretical interpretation of the abnormal 5D0→7F4 intensity based on the Eu3+ local coordination in the Na9[EuW10O36] • 14H2O polyoxometalate [J].
Ferreira, R. A. Sa ;
Nobre, S. S. ;
Granadeiro, C. M. ;
Nogueira, H. I. S. ;
Carlos, L. D. ;
Malta, O. L. .
JOURNAL OF LUMINESCENCE, 2006, 121 (02) :561-567
[6]   Synthesis and photocatalytic performance of novel CdS quantum dots sensitized Bi2WO6 photocatalysts [J].
Ge, Lei ;
Liu, Jing .
MATERIALS LETTERS, 2011, 65 (12) :1828-1831
[7]   Luminescent properties of Yb3+-doped hexagonal Ln3BWO9 (Ln = Gd, Y) [J].
Krut'ko, V. A. ;
Popov, A. V. ;
Voronko, Yu. K. ;
Chudinova, N. N. .
INORGANIC MATERIALS, 2010, 46 (08) :900-905
[8]   Crystal structure and vibrational properties of nonlinear Eu3BWO9 and Nd3BWO9 crystals [J].
Maczka, M ;
Tomaszewski, P ;
Stepien-Damm, J ;
Majchrowski, A ;
Macalik, L ;
Hanuza, J .
JOURNAL OF SOLID STATE CHEMISTRY, 2004, 177 (10) :3595-3602
[9]   Growth and spectroscopic characterization of Nd3BWO9 single crystal [J].
Majchrowski, A ;
Michalski, E ;
Brenier, A .
JOURNAL OF CRYSTAL GROWTH, 2003, 247 (3-4) :467-471
[10]   Fluorescence spectra of Eu3+:Ln(2)O(2)S (Ln=Y,La,Gd) powder phosphors [J].
Reddy, KR ;
Annapurna, K ;
Buddhudu, S .
MATERIALS RESEARCH BULLETIN, 1996, 31 (11) :1355-1359