Macroporous Monolithic Polymers: Preparation and Applications

被引:52
作者
Dario Arrua, Ruben [1 ]
Cristina Strumia, Miriam [1 ]
Alvarez Igarzabal, Cecilia Ines [1 ]
机构
[1] Univ Nacl Cordoba, Dept Quim Organ, Fac Ciencias Quim, RA-5000 Cordoba, Argentina
关键词
macroporous monoliths; macroporous polymers; chemical modification; SOLID-PHASE EXTRACTION; PERFORMANCE LIQUID-CHROMATOGRAPHY; MOLECULARLY IMPRINTED POLYMERS; OPENING METATHESIS POLYMERIZATION; CATION-EXCHANGE CHROMATOGRAPHY; SUPERCRITICAL CARBON-DIOXIDE; HIGH-FLOW CHARACTERISTICS; LESS COMMON APPLICATIONS; IN-SITU POLYMERIZATION; STABLE FREE-RADICALS;
D O I
10.3390/ma2042429
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In the last years, macroporous monolithic materials have been introduced as a new and useful generation of polymers used in different fields. These polymers may be prepared in a simple way from a homogenous mixture into a mold and contain large interconnected pores or channels allowing for high flow rates at moderate pressures. Due to their porous characteristics, they could be used in different processes, such as stationary phases for different types of chromatography, high-throughput bioreactors and in microfluidic chip applications. This review reports the contributions of several groups working in the preparation of different macroporous monoliths and their modification by immobilization of specific ligands on the products for specific purposes.
引用
收藏
页码:2429 / 2466
页数:38
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