POSS-embedded supramolecular hyperbranched polymers constructed from a 1→7 branching monomer with controllable morphology transitions

被引：31

作者：

Wang, Xing ^{[1
]}

Yang, Yanyu ^{[1
,2
]}

Fan, Linfeng ^{[1
,3
]}

Yang, Fei ^{[1
,3
]}

Wu, Decheng ^{[1
,3
]}

机构：

[1] Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China

[2] Zhengzhou Univ, Coll Mat Sci & Engn, Zhengzhou 450052, Peoples R China

[3] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

来源：

SCIENCE CHINA-CHEMISTRY | 2018年 / 61卷 / 03期

基金：

中国国家自然科学基金;

关键词：

POSS-embedded polymer; supramolecular hyperbranched polymer; host-guest interaction; morphology transition; FABRICATION; PH; POLYMERIZATION; ARCHITECTURE; AMPHIPHILES; COMPLEXES; MOLECULES; SCAFFOLDS; HYDROGEL; DELIVERY;

D O I：

10.1007/s11426-017-9168-3

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The research on the supramolecular hyperbranched polymers (SHPs) that combines the advantages of supramolecular polymer and hyperbranched architecture has attracted considerable interests in many applications. Here we demonstrate a simple approach to prepare POSS-embedded supramolecular hyperbranched polymers (POSS-SHPs) with varied morphology and size by controlling monomer concentration and mixed solvents. The SHPs formations can further transfer into the core-shell structured micelles by addition of competitive guests based on the double supramolecular driving forces.

引用

收藏

页码：311 / 318

页数：8

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