Recent Advances in Stereoselective Synthesis of 1,3-Dienes

被引:116
|
作者
De Paolis, Michael [1 ]
Chataigner, Isabelle [1 ]
Maddaluno, Jacques [1 ]
机构
[1] Univ Rouen, UMR CNRS COBRA 6014, F-76821 Mont St Aignan, France
来源
关键词
Conjugated dienes; Ene-ene coupling; Ene-yne coupling; Isomerization; Organocatalysis; Stereoselective synthesis; Transition metals; Yne-yne coupling; CROSS-COUPLING REACTION; CATALYZED REDUCTIVE COUPLINGS; BOND-FORMING HYDROGENATION; CONJUGATED DIENOIC ESTERS; STEREOCONTROLLED SYNTHESIS; REGIOSELECTIVE-SYNTHESIS; SELECTIVE SYNTHESIS; ALKYLIDENE COMPLEXES; EFFICIENT SYNTHESIS; CARBON-CARBON;
D O I
10.1007/128_2012_320
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The aim of this review is to present the latest developments in the stereoselective synthesis of conjugated dienes, covering the period 2005-2010. Since the use of this class of compounds is linked to the nature of their appendages (aryls, alkyls, electron-withdrawing, and heterosubstituted groups), the review has been categorized accordingly and illustrates the most representative strategies and mechanisms to access these targets.
引用
收藏
页码:87 / 146
页数:60
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