Material and device characteristics of InAs/GaAsSb sub-monolayer quantum dot solar cells

被引:12
作者
Kim, Yeongho [1 ]
Ban, Keun-Yong [1 ]
Zhang, Chaomin [1 ]
Honsberg, Christiana B. [1 ]
机构
[1] Arizona State Univ, Sch Elect Comp & Energy Engn, Tempe, AZ 85287 USA
基金
美国国家科学基金会;
关键词
MATRIX; GROWTH;
D O I
10.1063/1.4933272
中图分类号
O59 [应用物理学];
学科分类号
摘要
We have studied the material and photovoltaic characteristics of InAs/GaAsSb sub-monolayer quantum dot solar cells (QDSCs) with different Sb contents of 0%, 5%, 15%, and 20%. All QDSCs exhibit an extended external quantum efficiency (EQE) response in the wavelength range of 960-1000 nm that corresponds to sub-bandgap photon absorption. As Sb content increases from 5% to 20%, the cutoff wavelength in the EQE extends towards longer wavelength whilst the EQE in the wavelength region of 300-880 nm is lowered due to increased defect density. Compared to the QDSC (Sb 0%), an Sb incorporation of 5% enhances the short-circuit current density from 20.65 to 22.15 mA/cm(2) induced by Sb surfactant effect. Since the open-circuit voltage and fill factor of the QDSC (Sb 5%) are comparable to those of the QDSC (Sb 0%), an enhancement in solar cell efficiency (10.5%) of the QDSC (Sb 5%) is observed. Further increasing Sb content to 15% and 20% results in the degradation of solar cell performance due to increased nonradiative recombination and large valence band offset in a type-II band line-up. (C) 2015 AIP Publishing LLC.
引用
收藏
页数:5
相关论文
共 29 条
[1]   Reducing carrier escape in the InAs/GaAs quantum dot intermediate band solar cell [J].
Antolin, E. ;
Marti, A. ;
Farmer, C. D. ;
Linares, P. G. ;
Hernandez, E. ;
Sanchez, A. M. ;
Ben, T. ;
Molina, S. I. ;
Stanley, C. R. ;
Luque, A. .
JOURNAL OF APPLIED PHYSICS, 2010, 108 (06)
[2]   THE MEASUREMENT OF THREADING DISLOCATION DENSITIES IN SEMICONDUCTOR CRYSTALS BY X-RAY-DIFFRACTION [J].
AYERS, JE .
JOURNAL OF CRYSTAL GROWTH, 1994, 135 (1-2) :71-77
[3]   Observation of band alignment transition in InAs/GaAsSb quantum dots by photoluminescence [J].
Ban, Keun-Yong ;
Kuciauskas, Darius ;
Bremner, Stephen P. ;
Honsberg, Christiana B. .
JOURNAL OF APPLIED PHYSICS, 2012, 111 (10)
[4]   Use of a GaAsSb buffer layer for the formation of small, uniform, and dense InAs quantum dots [J].
Ban, Keun-Yong ;
Bremner, Stephen P. ;
Liu, Guangming ;
Dahal, Som N. ;
Dippo, Patricia C. ;
Norman, Andrew G. ;
Honsberg, Christiana B. .
APPLIED PHYSICS LETTERS, 2010, 96 (18)
[5]   INAS QUANTUM DOTS IN A SINGLE-CRYSTAL GAAS MATRIX [J].
BRANDT, O ;
TAPFER, L ;
PLOOG, K ;
BIERWOLF, R ;
HOHENSTEIN, M ;
PHILLIPP, F ;
LAGE, H ;
HEBERLE, A .
PHYSICAL REVIEW B, 1991, 44 (15) :8043-8053
[6]   Impact of stress relaxation in GaAsSb cladding layers on quantum dot creation in InAs/GaAsSb structures grown on GaAs (001) [J].
Bremner, S. P. ;
Ban, K-Y ;
Faleev, N. N. ;
Honsberg, C. B. ;
Smith, D. J. .
JOURNAL OF APPLIED PHYSICS, 2013, 114 (10)
[7]   Identification of candidate material systems for quantum dot solar cells including the effect of strain [J].
Dahal, Som N. ;
Bremner, Stephen P. ;
Honsberg, Christiana B. .
PROGRESS IN PHOTOVOLTAICS, 2010, 18 (04) :233-239
[8]   InAs/GaAsSb quantum dot solar cells [J].
Hatch, Sabina ;
Wu, Jiang ;
Sablon, Kimberly ;
Phu Lam ;
Tang, Mingchu ;
Jiang, Qi ;
Liu, Huiyun .
OPTICS EXPRESS, 2014, 22 (09) :A679-A685
[9]   Effect of strain compensation on quantum dot enhanced GaAs solar cells [J].
Hubbard, S. M. ;
Cress, C. D. ;
Bailey, C. G. ;
Raffaelle, R. P. ;
Bailey, S. G. ;
Wilt, D. M. .
APPLIED PHYSICS LETTERS, 2008, 92 (12)
[10]   MICROSTRUCTURAL EVOLUTION DURING THE HETEROEPITAXY OF GE ON VICINAL SI(100) [J].
KRISHNAMURTHY, M ;
DRUCKER, JS ;
VENABLES, JA .
JOURNAL OF APPLIED PHYSICS, 1991, 69 (09) :6461-6471