Selective Palladium-Catalyzed Hydroformylation of Alkynes to ,-Unsaturated Aldehydes

被引：72

作者：

Fang, Xianjie ^{[1
]}

Zhang, Min ^{[1
]}

Jackstell, Ralf ^{[1
]}

Beller, Matthias ^{[1
]}

机构：

[1] Univ Rostock, Leibniz Inst Katalyse eV, D-18059 Rostock, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 17期

关键词：

alkynes; hydroformylation; hydrogenation; palladium; -unsaturated aldehydes; ZWITTERIONIC RHODIUM COMPLEX; REGIOSELECTIVE HYDROFORMYLATION; ALKOXYCARBONYLATION; ENYNES; METHOXYCARBONYLATION; MECHANISM; ALKENES; ETHENE;

D O I：

10.1002/anie.201300759

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Atom-efficient: A selective palladium catalyst system is used for the hydroformylation of alkynes (see picture). In this syngas reaction, various alkynes were smoothly transformed to synthetically interesting α,β-unsaturated aldehydes in good yields with high regio- and stereoselectivity. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：4645 / 4649

页数：5

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