Emissive molecular nanomagnets: introducing optical properties in triangular oximato {Mn3III} SMMs from the deliberate replacement of simple carboxylate ligands with their fluorescent analogues

被引：27
作者：
Alexandropoulos, Dimitris I. [1 ]
Mowson, Andrew M. [2 ]
Pilkington, Melanie [1 ]
Bekiari, Vlasoula [3 ]
Christou, George [2 ]
Stamatatos, Theocharis C. [1 ]
机构：
[1] Brock Univ, Dept Chem, St Catharines, ON L2S 3A1, Canada
[2] Univ Florida, Dept Chem, Gainesville, FL 32611 USA
[3] Technol Educ Inst Messolonghi, Dept Aquaculture & Fisheries Management, Mesolongion 30200, Greece
来源：
DALTON TRANSACTIONS | 2014年 / 43卷 / 05期
基金：
美国国家科学基金会; 加拿大自然科学与工程研究理事会;
关键词：
MAGNETIC-ANISOTROPY; SINGLE; COMPLEXES;
D O I：
10.1039/c3dt52571f
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The targeted replacement of acetate groups in the optically inactive [(Mn3O)-O-III(O2CMe)(3)(mpko)(3)](ClO4) single-molecule magnet with their naphthalene, anthracene, and pyrene fluorescent analogues has led to three new emissive SMMs with enhanced photoluminescence properties and potential applications in the field of molecular electronics.
引用
收藏
页码：1965 / 1969
页数：5
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