N-(Hetero)arylations with Metalated (Hetero)aryls: Recent Advances in First-Row Transition-Metal-Mediated Cross-Couplings

被引:17
作者
Ribaucourt, Aubert [1 ]
Cossy, Janine [1 ]
机构
[1] PSL Univ, Mol Macromol Chem & Mat C3M, ESPCI Paris, CNRS, F-75005 Paris, France
关键词
amination; cross-coupling; nonprecious metal; umpolung; oxidative amination; CATALYZED ELECTROPHILIC AMINATION; C-N; ARYL BROMIDES; BORONIC ACIDS; POLYFUNCTIONAL ARYL; ARYLBORONIC ACIDS; TERTIARY-AMINES; COPPER; PALLADIUM; ARYLATION;
D O I
10.1021/acscatal.0c02805
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Transition-metal-catalyzed C(sp(2))-N bond forming reactions represent a very active field of research in chemistry. This review outlines the recent developments of the first-row transition-metal-catalyzed non-Buchwald-Hartwig cross-couplings (i.e., not taking place between a (hetero)aryl (pseudo)halide and an amine or other nitrogen-containing derivatives). The oxidative and umpolung cross-couplings represent the two main types of transformations discussed in this review.
引用
收藏
页码:10127 / 10148
页数:22
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