RAFT copolymerization of itaconic anhydride and 2-methoxyethyl acrylate: a multifunctional scaffold for preparation of "clickable" gold nanoparticles

被引:15
作者
Javakhishvili, Irakli [1 ]
Kasama, Takeshi [2 ]
Jankova, Katja [1 ]
Hvilsted, Soren [1 ]
机构
[1] Tech Univ Denmark, Danish Polymer Ctr, Dept Chem & Biochem Engn, DK-2800 Kongens Lyngby, Denmark
[2] Tech Univ Denmark, Ctr Elect Nanoscopy, DK-2800 Kongens Lyngby, Denmark
关键词
LIVING RADICAL POLYMERIZATION; POLY(2-METHOXYETHYL ACRYLATE); TERMINAL ALKYNES; WATER-STRUCTURE; CHEMISTRY; CYCLOADDITION; SURFACE; UPDATE; AZIDES;
D O I
10.1039/c3cc41887a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
RAFT copolymerization of 2-methoxyethyl acrylate and itaconic anhydride - a monomer derived from renewable resources - is carried out in a controlled fashion. The copolymer allows preparation of gold nanoparticles with abundant surficial carboxyl and alkyne functional groups that are dendronized via Cu(I)-mediated "click" reaction.
引用
收藏
页码:4803 / 4805
页数:3
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