Covalent organic frameworks

被引：2624

作者：

Feng, Xiao ^{[1
,2
]}

Ding, Xuesong ^{[1
]}

Jiang, Donglin ^{[1
,3
]}

机构：

[1] Natl Inst Nat Sci, Inst Mol Sci, Dept Mat Mol Sci, Okazaki, Aichi 4448787, Japan

[2] Beijing Inst Technol, Coll Mat Sci & Engn, Beijing 100081, Peoples R China

[3] Japan Sci & Technol Agcy JST, Precursory Res Embryon Sci & Technol PRESTO, Chiyoda Ku, Tokyo 1020075, Japan

来源：

CHEMICAL SOCIETY REVIEWS | 2012年 / 41卷 / 18期

关键词：

TRIAZINE-BASED FRAMEWORKS; HYDROGEN STORAGE; CARBON-DIOXIDE; RETICULAR SYNTHESIS; 2D; CRYSTALLINE; ADSORPTION; METHANE; CONSTRUCTION; EQUILIBRIUM;

D O I：

10.1039/c2cs35157a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Covalent organic frameworks (COFs) are a class of crystalline porous polymers that allow the atomically precise integration of organic units to create predesigned skeletons and nanopores. They have recently emerged as a new molecular platform for designing promising organic materials for gas storage, catalysis, and optoelectronic applications. The reversibility of dynamic covalent reactions, diversity of building blocks, and geometry retention are three key factors involved in the reticular design and synthesis of COFs. This tutorial review describes the basic design concepts, the recent synthetic advancements and structural studies, and the frontiers of functional exploration.

引用

页码：6010 / 6022

页数：13

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