Glass-forming ability and crystallization of Mg-Ni amorphous alloys with Y addition

被引:5
作者
Liu Liyan [1 ]
Teng Xinying [1 ]
Wang Yongjie [2 ]
Liu Teng [1 ]
机构
[1] Univ Jinan, Sch Mat Sci & Engn, Jinan 250022, Peoples R China
[2] Univ Jinan, Sch Phys & Technol, Jinan 250022, Peoples R China
关键词
Mg-based amorphous alloy; glass forming ability; crystallization; micro-hardness; BULK METALLIC GLASSES; MECHANICAL-PROPERTIES; HYDROGEN STORAGE; MELT-SPUN; ND;
D O I
10.1007/s12598-012-0499-2
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Mg86.33Ni13.67-x Y (x) (x=0, 1, 3, 6, 10) amorphous alloys were obtained by single-roller melt-spinning technique and the effect of Y addition on the glass forming ability(GFA), crystallization and micro-hardness of Mg-Ni alloys were studied. The results show that the GFA of Mg86.33Ni13.67-x Y (x) (x=0, 1, 3, 6, 10) is improved successfully with the Y addition. The highest GFA appeares at x=6, while the reduced glass transition temperature (T (rg)) is 0.5225 and the supercooled liquid region(Delta T (x)) is 42.06 K; the position of the main diffraction halo is different for the alloys, and the maximum of the main diffraction halo of alloys with x=0, 1, 3 corresponds to the main peaks of a metastable fcc-Mg6Ni or fcc-Mg6Ni + Ni-Y intermetallic phases, and for the alloys with x=6, 10, it corresponds to Mg-Y and Ni-Y intermetallic phases; the micro-hardness of the alloys is improved with Y additions, and the highest micro-hardness is obtained at x=6 at.%, which is 960 MPa.
引用
收藏
页码:244 / 249
页数:6
相关论文
共 16 条
[1]   Influence of minor alloying additions on the glass-forming ability of Mg-Ni-La bulk metallic glasses [J].
Gonzalez, S. ;
Figueroa, I. A. ;
Todd, I. .
JOURNAL OF ALLOYS AND COMPOUNDS, 2009, 484 (1-2) :612-618
[2]   Effect of mischmetal substitution on the glass-forming ability of Mg-Ni-La bulk metallic glasses [J].
Gonzalez, S. ;
Figueroa, I. A. ;
Zhao, H. ;
Davies, H. A. ;
Todd, I. ;
Adeva, P. .
INTERMETALLICS, 2009, 17 (11) :968-971
[3]   Stabilization of metallic supercooled liquid and bulk amorphous alloys [J].
Inoue, A .
ACTA MATERIALIA, 2000, 48 (01) :279-306
[4]   Mechanical responses of Mg-based bulk metallic glasses [J].
Jian, S. -R. ;
Li, J. -B. ;
Chen, K. -W. ;
Jang, Jason S. -C. ;
Juang, J. -Y. ;
Wei, P-J ;
Lin, J-F. .
INTERMETALLICS, 2010, 18 (10) :1930-1935
[5]   Hydrogen desorption kinetics of melt-spun and hydrogenated Mg90Ni10 and Mg80Ni10Y10 using in situ synchrotron, X-ray diffraction and thermogravimetry [J].
Kalinichenka, Siarhei ;
Roentzsch, Lars ;
Baehtz, Carsten ;
Kieback, Bernd .
JOURNAL OF ALLOYS AND COMPOUNDS, 2010, 496 (1-2) :608-613
[6]   Glass transition and crystallization of Mg-Ni-Nd metallic glasses studied by temperature-modulated DSC [J].
Lu, ZP ;
Liu, CT ;
Li, Y .
INTERMETALLICS, 2004, 12 (7-9) :869-874
[7]   Enhanced glass forming ability and plasticity in Mg-based bulk metallic glasses [J].
Park, E. S. ;
Kyeong, J. S. ;
Kim, D. H. .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2007, 449 :225-229
[8]   Change in mechanical properties during crystallization of amorphous Mg83Ni9Y8 [J].
Perez, P. ;
Garces, G. ;
Gonzalez, S. ;
Nitsche, H. ;
Sommer, F. ;
Adeva, P. .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2007, 462 (1-2) :211-214
[9]   Influence of partial replacement of cerium-rich mischmetal (CeMM) by yttrium on the crystallization and mechanical properties of amorphous Mg80Ni10CeMM10 alloy [J].
Perez, P. ;
Gonzalez, S. ;
Garces, G. .
INTERMETALLICS, 2007, 15 (03) :315-326
[10]   Phases formation during heating of Mg-Cu-Ag-Y bulk metallic glasses [J].
Soubeyroux, Jean-Louis ;
Puech, Sylvain .
JOURNAL OF ALLOYS AND COMPOUNDS, 2010, 495 (02) :330-333