Preparation of Pd/MOF and Ru/MOF Catalysts and Catalytic Performance for Hydrogenation and Cross-coupling Reactions

被引：9
作者：
Sawai, Tadashi [1 ]
Yonehara, Takahiro [1 ]
Yonezawa, Akihiro [1 ]
Sano, Makoto [1 ]
Suzuki, Toshimitsu [1 ]
Miyake, Takanori [1 ]
机构：
[1] Kansai Univ, Fac Environm & Urban Engn, Dept Chem Energy & Environm Engn, 3-3-35 Yamate Cho, Suita, Osaka 5648680, Japan
来源：
JOURNAL OF THE JAPAN PETROLEUM INSTITUTE | 2014年 / 57卷 / 01期
关键词：
Metal-organic framework; Hydrogenation; alpha; beta-Unsaturated aldehyde; Palladium catalyst; Ruthenium catalyst; Cross-coupling; METAL-ORGANIC FRAMEWORKS; ADSORPTION; MOFS;
D O I：
10.1627/jpi.57.58
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
Metal-organic framework compound consisting of terephthalic acid and chromium cation (TPA-Cr) was prepared by the hydrothermal method and characterized by XRD, N-2 adsorption-desoprtion isotherm, TGA-DTA and TEM. The prepared TPA-Cr was crystalline and phase-pure. Noble metal was supported on TPA-Cr by the conventional impregnation method. The specific Pd salt and solvent for impregnation significantly influenced the location of Pd. With [Pd(NH3)(4)(NO3)(2) dissolved in water, Pd was located in the micropores of TPA-Cr, whereas with PdCl2 dissolved in water or methanol, Pd was located on the external surface of TPA-Cr. Hydrogenation of cinnamaldehyde and crotonaldehyde, and cross-coupling between aryl bromides and phenylboronic acid were studied using Pd/TPA-Cr and Ru/TPA-Cr prepared as above. Hydrogenation of the two model aldehydes occurred in the micro- and meso-pores of TPA-Cr whereas cross-coupling reaction of builder compounds occurred mostly on the external surface of TPA-Cr.
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收藏
页码：58 / 64
页数：7
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