Porous organic polymers with anchored aldehydes: a new platform for post-synthetic amine functionalization en route for enhanced CO2 adsorption properties

被引：121

作者：

Guillerm, Vincent ^{[1
]}

Weselinski, Lukasz J. ^{[1
]}

Alkordi, Mohamed ^{[1
]}

Mohideen, M. Infas H. ^{[1
]}

Belmabkhout, Youssef ^{[1
]}

Cairns, Amy J. ^{[1
]}

Eddaoudi, Mohamed ^{[1
]}

机构：

[1] KAUST, Adv Membranes & Porous Mat Ctr, Div Phys Sci & Engn, Funct Mat Design Discovery & Dev Res Grp FMD3, Thuwal 239556900, Saudi Arabia

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 16期

关键词：

CARBON-DIOXIDE CAPTURE; MESOPOROUS SILICA; FLUE-GAS; FRAMEWORK; NETWORKS; CRYSTALLINE; AIR;

D O I：

10.1039/c3cc48228f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel porous organic polymer has been synthesized using the molecular building block approach to deliberately encompass aldehyde functionalities amenable to post functionalization. The resultant porous framework allows a facile, one-step quantitative and post-synthetic functionalization by amines, permitting enhanced CO2 sorption properties.

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收藏

页码：1937 / 1940

页数：4

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