catena-Poly[[(1,10-phenanthroline)cadmium(II)]-μ-2-(1,3-benzimidazol-2-ylsulfanyl)acetato-κ3N1,O:N3]

被引:1
作者
Cheng, Lin [1 ]
Sun, Yan-Yan [1 ]
Zhang, Ya-Wen [1 ]
Wang, Jian-Quan [1 ]
机构
[1] Southeast Univ, Sch Chem & Chem Engn, Nanjing 211189, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷
关键词
D O I
10.1107/S1600536808041044
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In title compound, [Cd(C9H6N2O2S)(C12H8N2)](n), the Cd-II atom is in a distorted tetragonal-pyramidal environment, coordinated by one chelating 1,10-phenanthroline ligand, one chelating 2-(1,3-benzimidazol-2-ylsulfanyl) acetate (bia) ligand bound through one N atom and one O atom of the carboxyl group, and one N atom from a second bia ligand. Each bia ligand acts as bridge between Cd-II ions, forming one-dimensional coordination polymers along [010], with a shortest Cd center dot center dot center dot Cd distance of 4.27 (2) angstrom.
引用
收藏
页码:M34 / U427
页数:9
相关论文
共 5 条
[1]  
*BRUK AXS INC, 2000, SMART SAINT
[2]  
MATTHEWS CJ, 1998, DALTON T, P1973
[3]  
Sheldrick G.M., 2000, SADABS
[4]   A short history of SHELX [J].
Sheldrick, George M. .
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 :112-122
[5]   Poly[{μ2-1,2-bis[4-(3-pyridyl)pyrimidin-2-ylsulfanyl]ethane}di-μ2-cyanidodicopper(I)] [J].
Zhang, Ya-Wen ;
Dong, Hua-Ze ;
Cheng, Lin .
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 :M868-U171