Ionogel based on biopolymer-silica interpenetrated networks: dynamics of confined ionic liquid with lithium salt

被引：25

作者：

Cerclier, Carole V. ^{[1
]}

Zanotti, Jean-Marc ^{[2
]}

Le Bideau, Jean ^{[1
]}

机构：

[1] Univ Nantes, CNRS, Inst Mat Jean Rauxel IMN, F-44322 Nantes 3, France

[2] CEA Saclay, Lab Lean Brillauin, UMR12, CEA,CNRS, F-91191 Gif Sur Yvette, France

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2015年 / 17卷 / 44期

关键词：

ENERGY-STORAGE; FAST DIFFUSION; CATION; ELECTROLYTES; NANOFIBERS; TRANSPORT;

D O I：

10.1039/c5cp04889c

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Obtaining solid-state electrolytes with good electrochemical performances remains challenging. Ionogels, i.e. solid host networks confining an ionic liquid, are promising as they keep the macroscopic properties of the liquid. However, confinement of an ionic liquid can imply important changes in its molecular dynamics, depending on the route of synthesis and on the confining network. We studied this effect on an imidazolium based ionic liquid with its lithium salt confined in a hybrid biopolymer-silica matrix. Dynamics of bulk and confined solution was probed by quasi-elastic neutron scattering (QENS) which revealed a weakly slowed dynamics of imidazolium-based ionic liquid inside the polymer-silica host network.

引用

页码：29707 / 29713

页数：7

共 43 条

[1] Effects of confinement on freezing and melting [J].

Alba-Simionesco, C. ;

Coasne, B. ;

Dosseh, G. ;

Dudziak, G. ;

Gubbins, K. E. ;

Radhakrishnan, R. ;

Sliwinska-Bartkowiak, M. .

JOURNAL OF PHYSICS-CONDENSED MATTER, 2006, 18 (06) :R15-R68

[2] Translational and Reorientational Dynamics of an Imidazolium-Based Ionic Liquid [J].

Aoun, Bachir ;

Gonzalez, Miguel A. ;

Ollivier, Jacques ;

Russina, Margarita ;

Izaola, Zunbeltz ;

Price, David L. ;

Saboungi, Marie-Louise .

JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2010, 1 (17) :2503-2507

[3]

Armand M, 2009, NAT MATER, V8, P621, DOI [10.1038/NMAT2448, 10.1038/nmat2448]

[4] DAVE: A Comprehensive Software Suite for the Reduction, Visualization, and Analysis of Low Energy Neutron Spectroscopic Data [J].

Azuah, Richard Tumanjong ;

Kneller, Larry R. ;

Qiu, Yiming ;

Tregenna-Piggott, Philip L. W. ;

Brown, Craig M. ;

Copley, John R. D. ;

Dimeo, Robert M. .

JOURNAL OF RESEARCH OF THE NATIONAL INSTITUTE OF STANDARDS AND TECHNOLOGY, 2009, 114 (06) :341-358

[5] Hydrophobic, highly conductive ambient-temperature molten salts [J].

Bonhote, P ;

Dias, AP ;

Papageorgiou, N ;

Kalyanasundaram, K ;

Gratzel, M .

INORGANIC CHEMISTRY, 1996, 35 (05) :1168-1178

[6] All Solid-State Symmetrical Activated Carbon Electrochemical Double Layer Capacitors Designed with Ionogel Electrolyte [J].

Brachet, M. ;

Brousse, T. ;

Le Bideau, J. .

ECS ELECTROCHEMISTRY LETTERS, 2014, 3 (11) :A112-A115

[7]

Brachet M., 2015, ADV ENERGY MAT UNPUB

[8] Biopolymer based nanocomposite ionogels: high performance, sustainable and solid electrolytes [J].

Buchtova, Nela ;

Guyomard-Lack, Aurelie ;

Le Bideau, Jean .

GREEN CHEMISTRY, 2014, 16 (03) :1149-1152

[9] Nanocomposite hydrogels for cartilage tissue engineering: mesoporous silica nanofibers interlinked with siloxane derived polysaccharide [J].

Buchtova, Nela ;

Rethore, Gildas ;

Boyer, Cecile ;

Guicheux, Jerome ;

Rambaud, Frederic ;

Valle, Karine ;

Belleville, Philippe ;

Sanchez, Clement ;

Chauvet, Olivier ;

Weiss, Pierre ;

Le Bideau, Jean .

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN MEDICINE, 2013, 24 (08) :1875-1884

[10] The dynamics of cations in pyridinium-based ionic liquids by means of quasielastic- and inelastic neutron scattering [J].

Burankova, Tatsiana ;

Reichert, Elena ;

Fossog, Verlaine ;

Hempelmann, Rolf ;

Embs, Jan Peter .

JOURNAL OF MOLECULAR LIQUIDS, 2014, 192 :199-207

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