Environmental benefits of methanesulfonic acid: Comparative properties and advantages

被引：318

作者：

Gernon, MD ^{[1
]}

Wu, M ^{[1
]}

Buszta, T ^{[1
]}

Janney, P ^{[1
]}

机构：

[1] Elf Atochem NA, KoP Tech Ctr, King Of Prussia, PA 19406 USA

来源：

GREEN CHEMISTRY | 1999年 / 1卷 / 03期

关键词：

D O I：

10.1039/a900157c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This paper reviews some chemical and physical characteristics of methanesulfonic acid and the short-chain alkanesulfonic acids in general. The aqueous solubility of metal methanesulfonates, the conductivity of aqueous methanesulfonic acid (MSA) solutions and the low toxicity of MSA all make MSA(aq) an ideal electrolyte for many electrochemical processes, especially those involving tin and lead. Aspects of aqueous process effluent treatment, acid recovery and metal alkanesulfonate salt preparation are also environmentally favorable. Emphasis in this paper is given to rationalizing the rapidly growing commercial preference for MSA(aq) as an electrochemical electrolyte, especially with respect to the substitution of MSA for HBF4 in the electroplating of Sn/Pb solder. Economic aspects of MSA are also considered.

引用

页码：127 / 140

页数：14

共 45 条

[1] [Anonymous], CHEM SULPHONIC ACIDS
[2] MICROBIAL-DEGRADATION OF METHANESULFONIC-ACID - A MISSING LINK IN THE BIOGEOCHEMICAL SULFUR CYCLE
BAKER, SC
KELLY, DP
MURRELL, JC
[J]. NATURE, 1991, 350 (6319) : 627 - 628
[3] ELECTROCHEMICAL GENERATION OF SOLUBLE AND REACTIVE CADMIUM, LEAD, AND THALLIUM CATIONS IN NONCOORDINATING SOLVENTS - RELATIVE STRENGTHS OF PERCHLORATE, TETRAFLUOROBORATE, AND HEXAFLUOROPHOSPHATE LIGATION IN DICHLOROMETHANE AND BENZENE
BOND, AM
ELLIS, SR
HOLLENKAMP, AF
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (16) : 5293 - 5297
[4] CAPELATO MD, 1995, J APPL ELECTROCHEM, V25, P408
[5] GERNON M, 1996, Patent No. 5520794
[6] GERNON MD, 1996, Patent No. 0711753
[7] GERNON MD, 1996, Patent No. 5491247
[8] GERNON MD, 1997, Patent No. 798985
[9] GERNON MD, 1998, P 12 ANN INT FOR EL
[10] GONZALEZ JA, 1991, THESIS U BRIT COLUMB, P6

← 1 2 3 4 5 →