Recent Developments in Transition Metal-Free Cross-Dehydrogenative Coupling Reactions for C-C Bond Formation

被引：52

作者：

Batra, Aanchal ^{[1
]}

Singh, Kamal Nain ^{[2
,3
]}

机构：

[1] Mehr Chand Mahajan DAV Coll Women, PG Dept Chem, Sec 36-A, Chandigarh 160036, India

[2] Panjab Univ, Dept Chem, Chandigarh 160014, India

[3] Panjab Univ, Ctr Adv Studies Chem, Chandigarh 160014, India

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2020年 / 2020卷 / 43期

关键词：

C-C bond formation; Metal-free coupling; Cross-dehydrogenative coupling; C-H activation; functionalization; Oxidative coupling; H ACTIVATION; FORMING REACTIONS; MOLECULAR-OXYGEN; TERTIARY-AMINES; FREE ACYLATION; CYCLIC ETHERS; IODINE; CARBON; OXIDATION; FUNCTIONALIZATION;

D O I：

10.1002/ejoc.202000785

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In recent years, carbon-carbon (C-C) bond formation, by directly connecting two different C-H bonds under oxidative conditions, has attracted much attention in academia and industries. Also known as Cross-Dehydrogenative Coupling (CDC), this methodology is an eco-friendly, cost and step economic as well as superior alternative to classical C-C coupling reactions. The catalytic functionalization of C-H bonds using transition metals is an interesting research topic and is extensively reported, but limited surveys are known for non-metal catalysed processes. This review briefly describes on the recent developments in cross-dehydrogenative coupling reactions for C-C bond formation with different oxidants under metal free conditions.

引用

页码：6676 / 6703

页数：28

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