Epoxidation of alkenes by a readily prepared and highly active and reusable heterogeneous molybdenum-based catalyst

被引：55
作者：
Grivani, G
Tangestaninejad, S [1 ]
Habibi, MH
Mirkhani, V
Moghadam, M
机构：
[1] Isfahan Univ, Dept Chem, Esfahan 81746, Iran
[2] Univ Yasuj, Dept Chem, Yasuj 75914, Iran
来源：
APPLIED CATALYSIS A-GENERAL | 2006年 / 299卷
关键词：
molybdenum carbonyl; heterogeneous catalyst; epoxidation; tert-butylhydroperoxide;
D O I：
10.1016/j.apcata.2005.10.032
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Polymer-bound piperazine was readily prepared from Merrifield resin and was used as a robust support for immobilization of molybdenum hexacarbonyl. This polymer-supported molybdenum catalyst shows high activity in the epoxidation of various alkenes in the presence of tertbutylhydroperoxide (TBHP). This new heterogenized molybdenum catalyst can be recovered and reused for eight times without loss of its activity. (c) 2005 Elsevier B.V. All rights reserved.
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收藏
页码：131 / 136
页数：6
相关论文
共 23 条
[1]  
AHN JH, 1996, J CHEM SOC CHEM COMM, P229
[2]  
BAHADURI S, 2000, HOMOGENEOUS CATALYSI, P183
[3]   IMMOBILIZED TRANSITION-METAL CARBONYLS AND RELATED CATALYSTS [J].
BAILEY, DC ;
LANGER, SH .
CHEMICAL REVIEWS, 1981, 81 (02) :109-148
[4]   Progress in enantioselective catalysis assessed from an industrial point of view [J].
Blaser, HU ;
Pugin, B ;
Spindler, F .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2005, 231 (1-2) :1-20
[5]   The role of catalysis for the clean production of fine chemicals [J].
Blaser, HU ;
Studer, M .
APPLIED CATALYSIS A-GENERAL, 1999, 189 (02) :191-204
[6]   Heterogeneous catalysis for fine chemicals production [J].
Blaser, HU .
CATALYSIS TODAY, 2000, 60 (3-4) :161-165
[7]   Solid-supported reagent strategies for rapid purification of combinatorial synthesis products [J].
Booth, RJ ;
Hodges, JC .
ACCOUNTS OF CHEMICAL RESEARCH, 1999, 32 (01) :18-26
[8]   Supported catalysts and their applications in synthetic organic chemistry [J].
de Miguel, YR ;
Brulé, E ;
Margue, RG .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 2001, (23) :3085-3094
[9]   Alkene epoxidations catalysed by Mo(VI) supported on Merrifield's polymer [J].
Gil, S ;
Gonzalez, R ;
Mestres, R ;
Sanz, V ;
Zapater, A .
REACTIVE & FUNCTIONAL POLYMERS, 1999, 42 (01) :65-72
[10]   Epoxidation of alkenes by a highly reusable and efficient polymer-supported molybdenum carbonyl catalyst [J].
Grivani, G ;
Tangestaninejad, S ;
Habibi, MH ;
Mirkhani, V .
CATALYSIS COMMUNICATIONS, 2005, 6 (06) :375-378
123