Synthesis and IR spectroscopic characterization of fluorinated graphite intercalation compounds with chlorinated derivatives of methane and ethane

被引：1

作者：

Pinakov, D. V. ^{[1
]}

Alferova, N. I. ^{[1
]}

Chekhova, G. N. ^{[1
]}

机构：

[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia

来源：

INORGANIC MATERIALS | 2012年 / 48卷 / 11期

基金：

俄罗斯基础研究基金会;

关键词：

MATRIX COMPOSITION; INCLUSION-COMPOUNDS;

D O I：

10.1134/S002016851211009X

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

We have synthesized (C2F (x) Br-0.01 center dot yG) (n) intercalation compounds with (C2F (x) Br-0.01) (n) as a host and G (dichloromethane, chloroform, carbon tetrachloride, and dichloroethane) as a guest (x and y are stoichiometric coefficients). The behavior of the functional groups in the guest and host subsystems has been studied by IR spectroscopy. We have examined the influence of the degree of fluorination of the polymer host (0.5 < x < 1.0) and the nature of the guest on the vibrational frequencies of the C-F and C-Cl bonds.

引用

页码：1153 / 1157

页数：5

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