Preparation and electromagnetic properties of Polyaniline(polypyrrole)-BaFe12O19/Ni0.8Zn0.2Fe2O4 ferrite nanocomposites

被引：80
作者：
Wang, Yan [1 ]
Huang, Ying [1 ]
Wang, Qiufen [1 ]
He, Qian [1 ]
Chen, Lin [1 ]
机构：
[1] NW Polytech Univ, Sch Sci, Minist Educ, Dept Appl Chem,Key Lab Space Appl Phys & Chem, Xian 710072, Peoples R China
来源：
APPLIED SURFACE SCIENCE | 2012年 / 259卷
关键词：
BaFe12O19; Ni0.8Zn0.2Fe2O4; Polyaniline; Polypyrrole; Electromagnetic properties; In situ polymerization; MAGNETIC-PROPERTIES; MICROWAVE-ABSORPTION; CARBON NANOTUBES; POLYANILINE; COMPOSITES; FABRICATION;
D O I：
10.1016/j.apsusc.2012.07.072
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The nanocomposite of hard (BaFe12O19)/soft ferrite (Ni0.8Zn0.2Fe2O4) was prepared by the sol-gel process, and then the polyaniline(PANI)/polypyrrole(PPY)-BaFe12O19/Ni0.8Zn0.2Fe2O4 was produced by in situ polymerization method. The structures, morphology and electromagnetic properties of the samples were characterized by various instruments. XRD, TEM, and FTIR analysis indicated that BaFe12O19/Ni0.8Zn0.2Fe2O4 ferrite were homogenously enwrapped by PANI(PPY) coating. The VSM and SDY-4 measurement show that the magnetic properties of the composites decreased with the increase in PANI(PPY) amount, However, the electrical conductivity is on the contrary. The electromagnetic properties of the composites were much better than BaFe12O19/Ni0.8Zn0.2Fe2O4 in the frequency range of 2-15 GHz, which mainly depends on the dielectric loss of PANI(PPY). A minimum reflection loss of the PANI(PPY)-BaFe12O19/Ni0.8Zn0.2Fe2O4 ferrite nanocomposite is -19.7 dB(-21.5 dB) at the frequency of 7.3 GHz (10.7 GHz). (C) 2012 Elsevier B. V. All rights reserved.
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收藏
页码：486 / 493
页数：8
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