Polymeric monovalent and divalent copper sulfates with 4.4′-bipyridine:: [CU2(SO4)(4,4′-bipy)2 • 6H2O]n and [CU(SO4)(4,4′-bipy)(H2O) • 0.5H2O]n

被引：18

作者：

Lah, N ^{[1
]}

Leban, I ^{[1
]}

机构：

[1] Univ Ljubljana, Fac Chem & Chem Technol, Ljubljana 1000, Slovenia

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2006年 / 9卷 / 01期

关键词：

copper complex; coordination polymer; sulfate coordination; bipyridine; solvothermal synthesis;

D O I：

10.1016/j.inoche.2005.07.026

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new composite inorganic-organic materials from the copper/sulfate/4,4'-bipyridine family have been isolated and structurally characterized. The structure of the monovalent compound exhibits double chains in which the two parallel -Cu-bipy- chains are interconnected through sulfate bridges. The divalent polymer consists of two-dimensional interwoven networks that are stacked together by hydrogen bonding between the layers. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：42 / 45

页数：4

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