Fast phase transitions under lack of local thermalization between successive elementary steps of the physical process are treated analytically. Non-Markovian master equations are derived for fast processes, which do not have enough time to reach energy or momentum thermalization during rapid phase change or freezing of a highly nonequilibrium system. These master equations provide a further physical basis for evolution and transport equations of the phase-field model used previously in the analyses of fast phase transitions.
机构:
Northwestern Univ, Dept Mat Sci & Engn, Evanston, IL 60208 USANorthwestern Univ, Dept Mat Sci & Engn, Evanston, IL 60208 USA
Johnson, A. E.
Voorhees, P. W.
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机构:
Northwestern Univ, Dept Mat Sci & Engn, Evanston, IL 60208 USA
Northwestern Univ, Dept Engn Sci & Appl Math, Evanston, IL 60208 USANorthwestern Univ, Dept Mat Sci & Engn, Evanston, IL 60208 USA