Linking of metal centres through boryl ligands: synthesis, spectroscopic and structural characterisation of symmetrically bridged boryl complexes

被引：23
作者：
Aldridge, S
Calder, RJ
Rossin, A
Dickinson, AA
Willock, DJ
Jones, C
Evans, DJ
Steed, JW
Light, EM
Coles, SJ
Hursthouse, MB
机构：
[1] Cardiff Univ, Dept Chem, Cardiff CF10 3TB, S Glam, Wales
[2] John Innes Ctr Plant Sci Res, Dept Biol Chem, Norwich NR4 7UH, Norfolk, England
[3] Kings Coll London, Dept Chem, London WC2R 2LS, England
[4] Univ Southampton, Dept Chem, Southampton SO17 1BJ, Hants, England
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2002年 / 09期
关键词：
D O I：
10.1039/b200695m
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Dinuclear species containing iron centres linked via various bridging boryl ligands have been synthesised and a combination of crystallographic, computational and spectroscopic (Mossbauer, IR, Raman) techniques have been used to probe the bonding in these complexes.
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页码：2020 / 2026
页数：7
相关论文
共 61 条
[1]   Synthesis and reactivity of transition metal complexes containing halogenated boryl ligands [J].
Aldridge, S ;
Calder, RJ ;
Baghurst, RE ;
Light, ME ;
Hursthouse, MB .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2002, 649 (1-2) :9-14
[2]   Convenient syntheses, spectroscopic and structural characterisation of bi-functional boranes [J].
Aldridge, S ;
Calder, RJ ;
Cunningham, MH ;
Malik, KMA ;
Steed, JW .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2000, 614 :188-194
[3]   Perfluoroaryl boryl complexes: synthesis, spectroscopic and structural characterisation of a complex containing the bis(pentafluorophenyl)boryl ligand [J].
Aldridge, S ;
Al-Fawaz, A ;
Calder, RJ ;
Dickinson, AA ;
Willock, DJ ;
Light, ME ;
Hursthouse, MB .
CHEMICAL COMMUNICATIONS, 2001, (18) :1846-1847
[4]   Linking of metal centres through boryl ligands:: synthesis, spectroscopic and structural characterisation of a symmetrically bridged boryl complex CpFe(CO)2BO2C6H2O2BFe(CO)2Cp [J].
Aldridge, S ;
Calder, RJ ;
Dickinson, AA ;
Willock, DJ ;
Steed, JW .
CHEMICAL COMMUNICATIONS, 2000, (15) :1377-1378
[5]   Hydroborations catalysed by transition metal complexes [J].
Beletskaya, I ;
Pelter, A .
TETRAHEDRON, 1997, 53 (14) :4957-5026
[6]   Transition metal complexes of boron - synthesis, structure and reactivity [J].
Braunschweig, H ;
Colling, M .
COORDINATION CHEMISTRY REVIEWS, 2001, 223 :1-51
[7]  
Braunschweig H, 1998, EUR J INORG CHEM, P291
[8]   Diboran(4)yl groups as ligands to transition metals [J].
Braunschweig, H ;
Ganter, B ;
Koster, M ;
Wagner, T .
CHEMISCHE BERICHTE, 1996, 129 (09) :1099-1101
[9]  
Braunschweig H, 1999, EUR J INORG CHEM, P1523
[10]  
Braunschweig H, 1998, EUR J INORG CHEM, P465
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