Palladium-catalyzed oxidative direct C-H/C-H cross coupling of anilides with β-keto esters

被引：26
作者：
Chan, Wai-Wing
Zhou, Zhongyuan
Yu, Wing-Yiu [1 ]
机构：
[1] Hong Kong Polytech Univ, State Key Lab Chirosci, Kowloon, Hong Kong, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 74期
关键词：
TERT-BUTYL HYDROPEROXIDE; ORTHO-ARYLATION; SIMPLE ARENES; OLEFINATION; METAL; ACTIVATION; ALDEHYDES; BONDS; ALKENYLATION; FUNCTIONALIZATION;
D O I：
10.1039/c3cc44769c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A Pd(II)-catalyzed oxidative direct C(sp(2))-H/C(sp(3))-H cross coupling of anilides with alpha-dicarbonyl compounds with Mn(OAc)(3)center dot 2H(2)O as the oxidant is reported and this protocol provides facile access to alpha-aryl malonates and beta-keto esters in good yields and regioselectivity.
引用
收藏
页码：8214 / 8216
页数：3
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