A Lead (II) 3D Coordination Polymer Based on a Marine Cyclic Peptide Motif

被引:8
|
作者
Chakraborty, Subrata [1 ]
Tyagi, Pooja [1 ]
Tai, Dar-Fu [1 ]
Lee, Gene-Hsiang [2 ]
Peng, Shie-Ming [2 ]
机构
[1] Natl Dong Hwa Univ, Dept Chem, Hualien 974, Taiwan
[2] Natl Taiwan Univ, Dept Chem, Taipei 106, Taiwan
关键词
natural product; cyclic peptide; lead; coordination polymer; crystal structures; macrocyclic chemistry; HISTONE DEACETYLASE INHIBITORS; SOLID-PHASE SYNTHESIS; ORGANIC FRAMEWORKS; NANOTUBES; TETRAPEPTIDES; COMPLEXES; BACTERIUM; IONS;
D O I
10.3390/molecules18054972
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
The crystal structure of a naturally occurring cyclic tetrapeptide cyclo(Gly-L-Ser-L-Pro-L-Glu) [cyclo(GSPE)] was obtained. The conformation of synthesized cyclo(GSPE) fixes the coordination to lead ion in a 1:1 ratio. This cyclo(GSPE)-Pb complex was constructed as an asymmetric 3D network in the crystalline state. The polymerization of a heavy metal ion with a rigid asymmetric cyclic tetrapeptide represents the first example of a new class of macrocyclic complexes.
引用
收藏
页码:4972 / 4985
页数:14
相关论文
共 50 条
  • [21] An unusual 3D coordination polymer based on bridging interactions of the nucleobase adenine
    García-Terán, JP
    Castillo, O
    Luque, A
    García-Couceiro, U
    Román, P
    Lezama, L
    INORGANIC CHEMISTRY, 2004, 43 (15) : 4549 - 4551
  • [22] Anion influence on transformations of a nonporous 3D to porous 3D coordination polymer
    Hashemi, Lida
    Morsali, Ali
    Buyukgungor, Orhan
    NEW JOURNAL OF CHEMISTRY, 2014, 38 (07) : 3187 - 3192
  • [23] 3D Cu(II) Cluster-Based Coordination Polymer: Increasing the Activity of Prothrombin and Preventing Postpartum Hemorrhage
    Pan, Qin
    Huang, Yi
    Dong, Yan
    Shi, Gang-Gang
    Wang, Ya-Hong
    JOURNAL OF CLUSTER SCIENCE, 2022, 33 (03) : 1177 - 1183
  • [24] Synthesis, Crystal Structure and Property of a 3D Octamolybdate Coordination Polymer Based on Nickel(II)-bis(triazole) System
    Wang Xiu-Li
    Zhao Dan
    Tian Ai-Xiang
    Liu Guo-Cheng
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2013, 29 (08) : 1668 - 1674
  • [25] Synthesis, characterization and comprehensive study of a 3D Co(II) coordination polymer antibacterial activity
    Parsaei, Mozhgan
    Akhbari, Kamran
    White, Jonathan
    JOURNAL OF MOLECULAR STRUCTURE, 2023, 1283
  • [26] Synthesis, crystal structure and photoluminescent properties of a 3D Zn(II) coordination polymer xdfhsdhfh
    Zhang, Xiao-Nan
    Cao, Xiao-Man
    Hao, Miao
    Kang, Bei-Bei
    Gao, Ming-Liang
    Han, Zheng-Bo
    INORGANIC CHEMISTRY COMMUNICATIONS, 2015, 52 : 23 - 26
  • [27] A novel 3D energetic coordination polymer containing Co(II) atoms in a pentanuclear cluster
    R.-F. Wu
    H.-P. Shi
    J.-R. Zhang
    F.-F. Chang
    Journal of Structural Chemistry, 2015, 56 : 1136 - 1142
  • [28] A novel 3D coordination polymer containing pentacoordinate cobalt(II) dimers with antiferromagnetic ordering
    Zeng, MH
    Gao, S
    Chen, XM
    INORGANIC CHEMISTRY COMMUNICATIONS, 2004, 7 (07) : 864 - 867
  • [29] Nano dispersion of 3D Cd(II) coordination polymer: synthetic blood plasma anticoagulant
    Rambabu, Darsi
    Pradeep, Chullikkattil P.
    Dhir, Abhimanew
    INORGANIC CHEMISTRY FRONTIERS, 2014, 1 (02): : 163 - 166
  • [30] A new 3D Mn(II) coordination polymer: Synthesis, crystal structure and photoelectrical property
    Luo, Yanan
    Kong, Miao
    Ren, Hao
    Gao, Yongwei
    Yu, Xiaoyang
    INORGANICA CHIMICA ACTA, 2020, 511