A Lead (II) 3D Coordination Polymer Based on a Marine Cyclic Peptide Motif

被引：8
|
作者：
Chakraborty, Subrata [1 ]
Tyagi, Pooja [1 ]
Tai, Dar-Fu [1 ]
Lee, Gene-Hsiang [2 ]
Peng, Shie-Ming [2 ]
机构：
[1] Natl Dong Hwa Univ, Dept Chem, Hualien 974, Taiwan
[2] Natl Taiwan Univ, Dept Chem, Taipei 106, Taiwan
来源：
MOLECULES | 2013年 / 18卷 / 05期
关键词：
natural product; cyclic peptide; lead; coordination polymer; crystal structures; macrocyclic chemistry; HISTONE DEACETYLASE INHIBITORS; SOLID-PHASE SYNTHESIS; ORGANIC FRAMEWORKS; NANOTUBES; TETRAPEPTIDES; COMPLEXES; BACTERIUM; IONS;
D O I：
10.3390/molecules18054972
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
The crystal structure of a naturally occurring cyclic tetrapeptide cyclo(Gly-L-Ser-L-Pro-L-Glu) [cyclo(GSPE)] was obtained. The conformation of synthesized cyclo(GSPE) fixes the coordination to lead ion in a 1:1 ratio. This cyclo(GSPE)-Pb complex was constructed as an asymmetric 3D network in the crystalline state. The polymerization of a heavy metal ion with a rigid asymmetric cyclic tetrapeptide represents the first example of a new class of macrocyclic complexes.
引用
收藏
页码：4972 / 4985
页数：14
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