CHEMICAL CHARACTERISTICS OF THE SOOT PRODUCED IN A HIGH-SPEED DIRECT INJECTION ENGINE OPERATED WITH DIESEL/BIODIESEL BLENDS

被引：11

作者：

Salamanca, Maurin ^{[1
]}

Agudelo, John R. ^{[2
]}

Mondragon, Fanor ^{[1
]}

Santamaria, Alexander ^{[1
]}

机构：

[1] Univ Antioquia, Energy Resources & Environm Chem Grp QUIREMA, Inst Chem, Medellin 1226, Colombia

[2] Univ Antioquia, Fac Engn, Grp Efficient Energy Management GIMEL, Medellin 1226, Colombia

来源：

COMBUSTION SCIENCE AND TECHNOLOGY | 2012年 / 184卷 / 7-8期

关键词：

Biodiesel; Chemical characterization; Chemical structure; Direct injection engine; Particulate matter; COMBUSTION; EMISSIONS;

D O I：

10.1080/00102202.2012.664007

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The aim of this work is to study the influence of the molecular structure of fatty acid esters present in biodiesel and their blends with diesel on the chemical characteristics of the emitted particulate matter. Biodiesel produced from palm oil, jatropha, castor oil and sachainchi was blended at 5% and 20% by volume with diesel. These fuels were used for the operation of a four-cylinder direct injection automotive diesel engine. The equivalent ratio was kept between 0.36 and 0.40, and the engine was operated at the point of minimum air-fuel ratio and maximum smoke opacity. The amount of particulate matter emitted was evaluated by opacity index. A marked reduction in soot formation was observed when the concentration of unsaturated methyl esters in the fuel was at low concentrations. This was accompanied by a reduction of the aliphatic carbon content in the particulate matter.

引用

页码：1179 / 1190

页数：12

共 16 条

[1] Biomass energy and the environmental impacts associated with its production and utilization [J].

Abbasi, Tasneem ;

Abbasi, S. A. .

RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2010, 14 (03) :919-937

[2] Impact of exhaust gas recirculation (EGR) on the oxidative reactivity of diesel engine soot [J].

Al-Qurashi, Khalid ;

Boehman, Andre L. .

COMBUSTION AND FLAME, 2008, 155 (04) :675-695

[3] Micro-FTIR study of soot chemical composition-evidence of aliphatic hydrocarbons on nascent soot surfaces [J].

Cain, Jeremy P. ;

Gassman, Paul L. ;

Wang, Hai ;

Laskin, Alexander .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2010, 12 (20) :5206-5218

[4]

Glassman I., 1996, COMBUSTION, V3rd, P631

[5] Biofuel Combustion Chemistry: From Ethanol to Biodiesel [J].

Kohse-Hoeinghaus, Katharina ;

Osswald, Patrick ;

Cool, Terrill A. ;

Kasper, Tina ;

Hansen, Nils ;

Qi, Fei ;

Westbrook, Charles K. ;

Westmoreland, Phillip R. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (21) :3572-3597

[6] Diesel emissions from biofuels derived from Spanish potential vegetable oils [J].

Lapuerta, M ;

Armas, O ;

Ballesteros, R ;

Fernández, J .

FUEL, 2005, 84 (06) :773-780

[7] Effect of biodiesel fuels on diesel engine emissions [J].

Lapuerta, Magin ;

Armas, Octavio ;

Rodriguez-Fernandez, Jose .

PROGRESS IN ENERGY AND COMBUSTION SCIENCE, 2008, 34 (02) :198-223

[8] Physical and chemical comparison of soot in hydrocarbon and biodiesel fuel diffusion flames: A study of model and commercial fuels [J].

Maricq, M. Matti .

COMBUSTION AND FLAME, 2011, 158 (01) :105-116

[9] FT-IR and 1H NMR characterization of the products of an ethylene inverse diffusion flame [J].

Santamaria, Alexander ;

Mondragon, Fanor ;

Molina, Alejandro ;

Marsh, Nathan D. ;

Eddings, Eric G. ;

Sarofim, Adel F. .

COMBUSTION AND FLAME, 2006, 146 (1-2) :52-62

[10] The influence of molecular structure of fatty acid monoalkyl esters on diesel combustion [J].

Schonborn, Alessandro ;

Ladommatos, Nicos ;

Williams, John ;

Allan, Robert ;

Rogerson, John .

COMBUSTION AND FLAME, 2009, 156 (07) :1396-1412

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