STRUCTURE OF THE FIRST NITROSOAMMINE COMPLEXES OF RUTHENIUM WITH A COORDINATED SULFATE ION: [Ru(NO)(NH3)4(SO4)](HSO4)•H2O AND [Ru(NO)(NH3)3Cl(SO4)]•2H2O

被引：0
作者：
Makhinya, A. N. [1 ,2 ]
Shusharina, E. A. [1 ,2 ]
Baidina, I. A. [1 ]
Il'in, M. A. [1 ,2 ]
机构：
[1] Russian Acad Sci, Siberian Div, AV Nikolaev Inst Inorgan Chem, Novosibirsk, Russia
[2] Novosibirsk State Univ, Novosibirsk, Russia
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2011年 / 52卷 / 05期
关键词：
ruthenium; nitroso complexes; ammine complexes; sulfate complexes; chlorine complexes; single crystal X-ray diffraction; thermogravimetry; IR spectroscopy; CRYSTAL-STRUCTURE;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
We present a thermogravimetric study of the thermolysis of trans-[Ru(NO)(NH3)(4)(H2O)](HSO4)SO4 in a helium atmosphere. The intermediate product of thermolysis (at 186 degrees C) is treated with a 2 M H2SO4 solution to obtain the first example of a sulfate ammine complex of nitrosoruthenium [Ru(NO)(NH3)(4)(SO4)](HSO4)center dot H2O (I) with a similar to 70% yield. The product of higher temperature thermolysis (220 degrees C) is treated with acids (H2SO4 and HCl) to obtain a triammine complex [Ru(NO)(NH3)(3)Cl(SO4)]center dot 2H(2)O (II). The structure of the compounds is found by single crystal XRD: Pna2(1) space group, a = 10.8005(2) angstrom, b = 14.9032(3) angstrom, c = 7.7603(1) angstrom) (I) and P2(1)/n space group, a = 8.9397(1) angstrom, b = 8.3276(1) angstrom, c = 13.8993(2) angstrom; beta = 97.358(1)degrees (II).
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页码：946 / 953
页数：8
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